dimethyl [(3S,5Z)-3-(4-methoxyphenyl)methoxy-2-oxo-5-undecenyl]phosphonate

Base Information

Chemical Name:dimethyl [(3S,5Z)-3-(4-methoxyphenyl)methoxy-2-oxo-5-undecenyl]phosphonate
CAS No.:1489263-06-0
Molecular Formula:C₂₁H₃₃O₆P
Molecular Weight:412.463
Hs Code.:

Synonyms:dimethyl [(3S,5Z)-3-(4-methoxyphenyl)methoxy-2-oxo-5-undecenyl]phosphonate

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Chemical Property of dimethyl [(3S,5Z)-3-(4-methoxyphenyl)methoxy-2-oxo-5-undecenyl]phosphonate

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Technology Process of dimethyl [(3S,5Z)-3-(4-methoxyphenyl)methoxy-2-oxo-5-undecenyl]phosphonate

There total 6 articles about dimethyl [(3S,5Z)-3-(4-methoxyphenyl)methoxy-2-oxo-5-undecenyl]phosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 1489263-04-8
(2S,4Z)-N-methoxy-2-(4-methoxyphenyl)methoxy-N-methyl-4-decenamide

: 756-79-6
dimethyl methane phosphonate

: 1489263-06-0
dimethyl [(3S,5Z)-3-(4-methoxyphenyl)methoxy-2-oxo-5-undecenyl]phosphonate

Guidance literature:: dimethyl methane phosphonate; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

(2S,4Z)-N-methoxy-2-(4-methoxyphenyl)methoxy-N-methyl-4-decenamide; In tetrahydrofuran; at -78 ℃; for 6h;
DOI:10.1016/j.tet.2014.04.040

Reference yield:

: 118949-49-8,139462-27-4
4-benzyl-3-[2-(4-methoxy-benzyloxy)-acetyl]-oxazolidin-2-one

: 1489263-06-0
dimethyl [(3S,5Z)-3-(4-methoxyphenyl)methoxy-2-oxo-5-undecenyl]phosphonate

Guidance literature:: Multi-step reaction with 4 steps

1.1: sodium hexamethyldisilazane / tetrahydrofuran / 0.5 h / -78 °C

1.2: -78 - -40 °C

2.1: dihydrogen peroxide; lithium hydroxide monohydrate / tetrahydrofuran; water / 3 h / 0 °C

3.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 3 h / 0 - 20 °C

4.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

4.2: 6 h / -78 °C

With dmap; n-butyllithium; lithium hydroxide monohydrate; dihydrogen peroxide; sodium hexamethyldisilazane; dicyclohexyl-carbodiimide; In tetrahydrofuran; hexane; dichloromethane; water;
DOI:10.1016/j.tet.2014.04.040

Reference yield:

: 98314-97-7
(Z)-2-octenyl iodide

: 1489263-06-0
dimethyl [(3S,5Z)-3-(4-methoxyphenyl)methoxy-2-oxo-5-undecenyl]phosphonate

Guidance literature:: Multi-step reaction with 4 steps

1.1: sodium hexamethyldisilazane / tetrahydrofuran / 0.5 h / -78 °C

1.2: -78 - -40 °C

2.1: dihydrogen peroxide; lithium hydroxide monohydrate / tetrahydrofuran; water / 3 h / 0 °C

3.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 3 h / 0 - 20 °C

4.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

4.2: 6 h / -78 °C

With dmap; n-butyllithium; lithium hydroxide monohydrate; dihydrogen peroxide; sodium hexamethyldisilazane; dicyclohexyl-carbodiimide; In tetrahydrofuran; hexane; dichloromethane; water;
DOI:10.1016/j.tet.2014.04.040