Technology Process of copper β-octabromo-meso-tris(p-CF3-phenyl)corrole
There total 3 articles about copper β-octabromo-meso-tris(p-CF3-phenyl)corrole which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Cu(C19H8N4(C6H4CF3)3);
With
bromine;
In
chloroform;
at 20 ℃;
for 1h;
With
pyridine;
In
chloroform;
for 1h;
DOI:10.1016/j.jinorgbio.2015.07.017
- Guidance literature:
-
Multi-step reaction with 2 steps
1: pyridine
2: sodium metabisulfite / water; chloroform; pyridine
With
sodium metabisulfite;
In
pyridine; chloroform; water;
DOI:10.1021/ja0113697
- Guidance literature:
-
With
sodium metabisulfite;
In
pyridine; chloroform; water;
to stirred soln. of Cu(III)-complex in CHCl3 added Br2 dissolved in CHCl3 over 15 min at room temp.; mixt. stirred for 1 h; pyridine dissolved in CHCl3 added dropwise over 15 min; soln. stirred for 1 h; aq. soln. of sodium metabisulfite added; org. layer sepd.; dried (anhyd. Na2SO4); solvent evapd.; purified by chromy. on silica gel (hexane/CH2Cl2 as eluent);
DOI:10.1021/ja0113697
