(2S,4R)-4-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)-3-oxoundecan-2-yl benzoate

Base Information

Chemical Name:(2S,4R)-4-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)-3-oxoundecan-2-yl benzoate
CAS No.:1334396-14-3
Molecular Formula:C₄₁H₆₆O₆Si₂
Molecular Weight:711.142
Hs Code.:

Synonyms:(2S,4R)-4-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)-3-oxoundecan-2-yl benzoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,4R)-4-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)-3-oxoundecan-2-yl benzoate

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Technology Process of (2S,4R)-4-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)-3-oxoundecan-2-yl benzoate

There total 1 articles about (2S,4R)-4-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)-3-oxoundecan-2-yl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (2S)-4-((2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)hydroxymethyl)-3-oxoundecan-2-yl benzoate

: 79271-56-0
triethylsilyl trifluoromethyl sulfonate

: (2S,4S)-4-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)-3-oxoundecan-2-yl benzoate

: 1334396-14-3
(2S,4R)-4-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)-3-oxoundecan-2-yl benzoate

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at -50 ℃; for 3h; Inert atmosphere;
DOI:10.1002/anie.201103117

Reference yield: 55.0%

: 1334396-14-3
(2S,4R)-4-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)-3-oxoundecan-2-yl benzoate

: 1334396-21-2
C₃₄H₆₄O₅Si₂

Guidance literature:: With lithium borohydride; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1002/anie.201103117

Reference yield:

: 1334396-14-3
(2S,4R)-4-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)-3-oxoundecan-2-yl benzoate

: 1334396-08-5
(R)-2-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)nonanal

Guidance literature:: Multi-step reaction with 2 steps

1: lithium borohydride / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

2: lead(IV) tetraacetate; sodium carbonate / dichloromethane / 2 h / 0 °C / Inert atmosphere

With lithium borohydride; lead(IV) tetraacetate; sodium carbonate; In tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.201103117