(R)-2-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)nonanal

Base Information

Chemical Name:(R)-2-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)nonanal
CAS No.:1334396-08-5
Molecular Formula:C₃₂H₅₈O₄Si₂
Molecular Weight:562.981
Hs Code.:

Synonyms:(R)-2-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)nonanal

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Chemical Property of (R)-2-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)nonanal

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Technology Process of (R)-2-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)nonanal

There total 4 articles about (R)-2-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)nonanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1334396-21-2
C₃₄H₆₄O₅Si₂

: 1334396-08-5
(R)-2-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)nonanal

Guidance literature:: With lead(IV) tetraacetate; sodium carbonate; In dichloromethane; at 0 ℃; for 2h; Inert atmosphere;
DOI:10.1002/anie.201103117

Reference yield:

: (2S)-4-((2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)hydroxymethyl)-3-oxoundecan-2-yl benzoate

: 1334396-08-5
(R)-2-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)nonanal

Guidance literature:: Multi-step reaction with 3 steps

1: 2,6-dimethylpyridine / dichloromethane / 3 h / -50 °C / Inert atmosphere

2: lithium borohydride / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

3: lead(IV) tetraacetate; sodium carbonate / dichloromethane / 2 h / 0 °C / Inert atmosphere

With 2,6-dimethylpyridine; lithium borohydride; lead(IV) tetraacetate; sodium carbonate; In tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.201103117

Reference yield:

: 1334396-14-3
(2S,4R)-4-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)-3-oxoundecan-2-yl benzoate

: 1334396-08-5
(R)-2-((S)-(2-(allyloxy)-6-((tert-butyldimethylsilyloxy)methyl)phenyl)(triethylsilyloxy)methyl)nonanal

Guidance literature:: Multi-step reaction with 2 steps

1: lithium borohydride / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

2: lead(IV) tetraacetate; sodium carbonate / dichloromethane / 2 h / 0 °C / Inert atmosphere

With lithium borohydride; lead(IV) tetraacetate; sodium carbonate; In tetrahydrofuran; dichloromethane;
DOI:10.1002/anie.201103117