(2-phenyl-ortho-carboranyl)2SO

Base Information

• Chemical Name: (2-phenyl-ortho-carboranyl)2SO
• CAS No.: 878540-78-4
• Molecular Formula: C₁₆H₃₀B₂₀OS
• Molecular Weight: 486.7
• Mol file: 878540-78-4.mol

Synonyms:(2-phenyl-ortho-carboranyl)2SO

Chemical Property of (2-phenyl-ortho-carboranyl)2SO

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2-phenyl-ortho-carboranyl)2SO

There total 1 articles about (2-phenyl-ortho-carboranyl)2SO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

thionyl chloride (7719-09-7) + 1-phenyl-1,2-closo-C2B10H11 (16390-61-7) → (2-phenyl-ortho-carboranyl)2SO (878540-78-4)

Guidance literature:

With BuLi; In diethyl ether; hexane; byproducts: LiCl; all manipulations under dry, O2-free N2 atm.; soln. of BuLi in hexane added to soln. of B compd. in Et2O at 0°C, soln. of SOCl2 in Et2O added, stirred for 1 h, warmed to room temp.; filtered, solvent removed in vac., washed with 60-80° petroleum ether, recrystd. from EtOAc-cyclohexane (1:9); elem. anal.;

DOI:10.1016/j.poly.2005.06.046

Reference yield: 66.0%

(2-phenyl-ortho-carboranyl)2SO (878540-78-4) → (2-phenyl-ortho-carboranyl)2S (878540-77-3)

Guidance literature:

With H₂; 10percent Pd on C; In acetic acid; H2 slowly bubbled through stirred suspn. of B compd. and 10% Pd on C for15 h; filtered, solvent removed;

DOI:10.1016/j.poly.2005.06.046

upstream raw materials:

thionyl chloride

1-phenyl-1,2-closo-C₂B₁₀H₁₁

Downstream raw materials:

(2-phenyl-ortho-carboranyl)2S