(2-phenyl-ortho-carboranyl)2S

Base Information

• Chemical Name: (2-phenyl-ortho-carboranyl)2S
• CAS No.: 878540-77-3
• Molecular Formula: C₁₆H₃₀B₂₀S
• Molecular Weight: 470.7
• Mol file: 878540-77-3.mol

Synonyms:(2-phenyl-ortho-carboranyl)2S

Chemical Property of (2-phenyl-ortho-carboranyl)2S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2-phenyl-ortho-carboranyl)2S

There total 2 articles about (2-phenyl-ortho-carboranyl)2S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

(2-phenyl-ortho-carboranyl)2SO (878540-78-4) → (2-phenyl-ortho-carboranyl)2S (878540-77-3)

Guidance literature:

With H₂; 10percent Pd on C; In acetic acid; H2 slowly bubbled through stirred suspn. of B compd. and 10% Pd on C for15 h; filtered, solvent removed;

DOI:10.1016/j.poly.2005.06.046

Reference yield: 49.0%

1-phenyl-1,2-closo-C2B10H11 (16390-61-7) + sulfur dichloride (10545-99-0) → (2-phenyl-ortho-carboranyl)2S (878540-77-3)

Guidance literature:

With BuLi; In diethyl ether; hexane; all manipulations under dry, O2-free N2 atm.; soln. of BuLi in hexane added to soln. of B compd. in Et2O at 0°C, soln. of SCl2 in Et2O added, stirred at ambient temp. for 2 h; dild. with ether, filtered, washed with water, dried over MgSO4, solventremoved in vac., crystals washed with 60-80° petroleum ether, re crystd. from benzene-hexane (1:1); elem. anal.;

DOI:10.1016/j.poly.2005.06.046

upstream raw materials:

1-phenyl-1,2-closo-C₂B₁₀H₁₁

sulfur dichloride

(2-phenyl-ortho-carboranyl)2SO