2-oxo-2-phenylethyl trifluoromethanesulfinate

Base Information

• Chemical Name: 2-oxo-2-phenylethyl trifluoromethanesulfinate
• CAS No.: 35896-47-0
• Molecular Formula: C₉H₇F₃O₃S
• Molecular Weight: 252.214
• Mol file: 35896-47-0.mol

Synonyms:2-oxo-2-phenylethyl trifluoromethanesulfinate

Chemical Property of 2-oxo-2-phenylethyl trifluoromethanesulfinate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-oxo-2-phenylethyl trifluoromethanesulfinate

There total 3 articles about 2-oxo-2-phenylethyl trifluoromethanesulfinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

potassium triflinate (41804-89-1) + α-bromoacetophenone (70-11-1) → 2-oxo-2-phenylethyl trifluoromethanesulfinate (35896-47-0)

Guidance literature:

iodide; In acetonitrile; in boiling acetonitrile, 48 h;

DOI:10.1021/ja00814a061

Reference yield: 75.0%

Langlois reagent (2926-29-6) + 2-diazo-acetophenone (3282-32-4) → 2-oxo-2-phenylethyl trifluoromethanesulfinate (35896-47-0)

Guidance literature:

With tert.-butylhydroperoxide; copper diacetate; In ethyl acetate; at 60 ℃; for 1h; Green chemistry;

Reference yield:

silver trifluoromethanesulfinate (35896-42-5) + α-bromoacetophenone (70-11-1) → 1-phenyl-2-((trifluoromethyl)sulfonyl)ethan-1-one (35896-48-1) + 2-oxo-2-phenylethyl trifluoromethanesulfinate (35896-47-0)

Guidance literature:

at 60°C, 24 h, mixing;

upstream raw materials:

potassium triflinate

α-bromoacetophenone

silver trifluoromethanesulfinate

Langlois reagent