4-tert-butylphenoxyferrocene

Base Information

Chemical Name:4-tert-butylphenoxyferrocene
CAS No.:704898-63-5
Molecular Formula:C₂₀H₂₂FeO
Molecular Weight:334.241
Hs Code.:

Synonyms:4-tert-butylphenoxyferrocene

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Chemical Property of 4-tert-butylphenoxyferrocene

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Technology Process of 4-tert-butylphenoxyferrocene

There total 1 articles about 4-tert-butylphenoxyferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1273-76-3
iodoferrocene

: 98-54-4
para-tert-butylphenol

: 704898-63-5
4-tert-butylphenoxyferrocene

Guidance literature:: With caesium carbonate; In further solvent(s); under Ar; CuI, 2,2,6,6-tetramethylheptane-3,5-dione, Fe complex, phenol and Cs2CO3 (0.05:0.12:1:2:2) dissolved in NMP; stirred at 110°C for 20 h; Et2O added; extd. with water; solvent evapd.; purified by column chromy.(silica, n-heptane); elem. anal.;
DOI:10.1021/om0497893

Reference yield: 67.0%

: 704898-63-5
4-tert-butylphenoxyferrocene

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 1258941-82-0
rac-1-(4-tert-butylphenoxy)-2,1'-bis(diphenylphosphanyl)ferrocene

Guidance literature:: With nBuLi; tetramethylethylenediamine; In hexane; nBuLi in n-hexane added dropwise to Fe-compd. and tmeda in anhydrous n-hexane, stirred for 12 h at ambient temp., cooled to -78°C, neat P-compd. added, stirred for 30 min at -78°C and 90 min at ambient temp.; H2O added, extracted with Et2O, dried with MgSO4, concentrated under reduced pressure, column chromy. (alumina, n-hexane/Et2O, 90:10, v/v), recrystallized from CHCl3, elem. anal.;
DOI:10.1002/ejic.201000722

Reference yield: 64.0%

: 704898-63-5
4-tert-butylphenoxyferrocene

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 1258941-81-9
rac-1-(4-tert-butylphenoxy)-2-(diphenylphosphanyl)ferrocene

Guidance literature:: With nBuLi; tetramethylethylenediamine; In hexane; nBuLi in n-hexane added dropwise to Fe-compd. and tmeda in anhydrous n-hexane, stirred for 12 h at ambient temp., cooled to -78°C, neat P-compd. added, stirred for 30 min at -78°C and for 90 min at ambient temp.; H2O added, extracted with Et2O, dried with MgSO4, concentrated under reduced pressure, column chromy. (alumina, n-hexane/Et2O = 95:5, v/v), elem. anal.;
DOI:10.1002/ejic.201000722