rac-1-(4-tert-butylphenoxy)-2-(diphenylphosphanyl)ferrocene

Base Information

• Chemical Name: rac-1-(4-tert-butylphenoxy)-2-(diphenylphosphanyl)ferrocene
• CAS No.: 1258941-81-9
• Molecular Formula: C₃₂H₃₁FeOP
• Molecular Weight: 518.418
• Mol file: 1258941-81-9.mol

Synonyms:

Chemical Property of rac-1-(4-tert-butylphenoxy)-2-(diphenylphosphanyl)ferrocene

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of rac-1-(4-tert-butylphenoxy)-2-(diphenylphosphanyl)ferrocene

There total 1 articles about rac-1-(4-tert-butylphenoxy)-2-(diphenylphosphanyl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

4-tert-butylphenoxyferrocene (704898-63-5) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → rac-1-(4-tert-butylphenoxy)-2-(diphenylphosphanyl)ferrocene (1258941-81-9)

Guidance literature:

With nBuLi; tetramethylethylenediamine; In hexane; nBuLi in n-hexane added dropwise to Fe-compd. and tmeda in anhydrous n-hexane, stirred for 12 h at ambient temp., cooled to -78°C, neat P-compd. added, stirred for 30 min at -78°C and for 90 min at ambient temp.; H2O added, extracted with Et2O, dried with MgSO4, concentrated under reduced pressure, column chromy. (alumina, n-hexane/Et2O = 95:5, v/v), elem. anal.;

DOI:10.1002/ejic.201000722

upstream raw materials:

4-tert-butylphenoxyferrocene

chloro-diphenylphosphine