2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosyluronamide 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosiduronamide

Base Information

• Chemical Name: 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosyluronamide 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosiduronamide
• CAS No.: 129729-14-2
• Molecular Formula: C₅₆H₆₀N₂O₁₁
• Molecular Weight: 937.099
• Mol file: 129729-14-2.mol

Synonyms:2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosyluronamide 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosiduronamide

Chemical Property of 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosyluronamide 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosiduronamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosyluronamide 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosiduronamide

There total 3 articles about 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosyluronamide 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosiduronamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.5%

2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosylurononitrile 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosidurononitrile (129729-13-1) → 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosyluronamide 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosiduronamide (129729-14-2)

Guidance literature:

With sodium hydroxide; dihydrogen peroxide; In acetone; for 20h; Ambient temperature;

DOI:10.1016/0008-6215(90)84204-8

Reference yield:

2,3,4,2',3',4'-hexa-O-benzyl-α,α-trehalose (1253692-55-5) → 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosyluronamide 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosiduronamide (129729-14-2)

Guidance literature:

Multi-step reaction with 3 steps

1: 94 percent / pyridine / 1,2-dichloro-ethane

2: acetonitrile; H₂O / 8 h / 25 °C

3: 82.5 percent / solid NaOH, aq. 30percent H₂O₂ / acetone / 20 h / Ambient temperature

With pyridine; sodium hydroxide; dihydrogen peroxide; In water; 1,2-dichloro-ethane; acetone; acetonitrile;

DOI:10.1016/0008-6215(90)84204-8

Reference yield:

2,3,4,2',3',4'-hexa-O-benzyl-6,6'-di-O-(trifluoromethyl)sulfonyl-α,α-trehalose (125177-98-2,129729-12-0) → 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosyluronamide 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosiduronamide (129729-14-2)

Guidance literature:

Multi-step reaction with 2 steps

1: acetonitrile; H₂O / 8 h / 25 °C

2: 82.5 percent / solid NaOH, aq. 30percent H₂O₂ / acetone / 20 h / Ambient temperature

With sodium hydroxide; dihydrogen peroxide; In water; acetone; acetonitrile;

DOI:10.1016/0008-6215(90)84204-8

upstream raw materials:

2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosylurononitrile 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosidurononitrile

2,3,4,2',3',4'-hexa-O-benzyl-α,α-trehalose

2,3,4,2',3',4'-hexa-O-benzyl-6,6'-di-O-(trifluoromethyl)sulfonyl-α,α-trehalose