2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosylurononitrile 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosidurononitrile

Base Information

• Chemical Name: 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosylurononitrile 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosidurononitrile
• CAS No.: 129729-13-1
• Molecular Formula: C₅₆H₅₆N₂O₉
• Molecular Weight: 901.069
• Mol file: 129729-13-1.mol

Synonyms:2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosylurononitrile 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosidurononitrile

Chemical Property of 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosylurononitrile 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosidurononitrile

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosylurononitrile 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosidurononitrile

There total 2 articles about 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosylurononitrile 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosidurononitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3,4,2',3',4'-hexa-O-benzyl-α,α-trehalose (1253692-55-5) → 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosylurononitrile 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosidurononitrile (129729-13-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 94 percent / pyridine / 1,2-dichloro-ethane

2: acetonitrile; H₂O / 8 h / 25 °C

With pyridine; In water; 1,2-dichloro-ethane; acetonitrile;

DOI:10.1016/0008-6215(90)84204-8

Reference yield:

potassium cyanide (151-50-8) + 2,3,4,2',3',4'-hexa-O-benzyl-6,6'-di-O-(trifluoromethyl)sulfonyl-α,α-trehalose (125177-98-2,129729-12-0) → 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosylurononitrile 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosidurononitrile (129729-13-1)

Guidance literature:

In water; acetonitrile; at 25 ℃; for 8h; Yield given;

DOI:10.1016/0008-6215(90)84204-8

Reference yield: 82.5%

2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosylurononitrile 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosidurononitrile (129729-13-1) → 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosyluronamide 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosiduronamide (129729-14-2)

Guidance literature:

With sodium hydroxide; dihydrogen peroxide; In acetone; for 20h; Ambient temperature;

DOI:10.1016/0008-6215(90)84204-8

upstream raw materials:

potassium cyanide

2,3,4,2',3',4'-hexa-O-benzyl-6,6'-di-O-(trifluoromethyl)sulfonyl-α,α-trehalose

2,3,4,2',3',4'-hexa-O-benzyl-α,α-trehalose

Downstream raw materials:

2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosyluronamide 2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-heptopyranosiduronamide