bis(benzyltriphenylphosphonium) bis(dithiooxalato-S,S')cuprate(II)

Base Information

• Chemical Name: bis(benzyltriphenylphosphonium) bis(dithiooxalato-S,S')cuprate(II)
• CAS No.: 38999-75-6
• Molecular Formula: C₄CuO₄S₄*2C₂₅H₂₂P
• Molecular Weight: 1010.7
• Mol file: 38999-75-6.mol

Synonyms:bis(benzyltriphenylphosphonium) bis(dithiooxalato-S,S')cuprate(II)

Chemical Property of bis(benzyltriphenylphosphonium) bis(dithiooxalato-S,S')cuprate(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(benzyltriphenylphosphonium) bis(dithiooxalato-S,S')cuprate(II)

There total 1 articles about bis(benzyltriphenylphosphonium) bis(dithiooxalato-S,S')cuprate(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

copper(II) choride dihydrate + benzyltriphenylphosphonium chloride (1100-88-5) + potassium 1,2-dithiooxalate (17148-97-9,20267-56-5) → bis(benzyltriphenylphosphonium) bis(dithiooxalato-S,S')cuprate(II) (38999-75-6)

Guidance literature:

In water; aq. soln. of C6H5CH2(C6H5)3PCl and CuCl2*2H2O (2:1 molar ratio) was added to equivalent amount of aq. soln. of K2S2C2O2 with stirring; pptd., filtered, allowed to dry in vac., dissolved in DMF, Et2O was added, cooled to ca. -10°C, allowed to stand for ca. 4h, elem. anal.;

DOI:10.1021/ja00316a028

Reference yield:

bis(benzyltriphenylphosphonium) bis(dithiooxalato-S,S')cuprate(II) (38999-75-6) → benzyltriphenylphosphonium (dithiooxalato-S,S')bis(triphenylphosphine)cuprate(I) (62392-88-5)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane; acetone

2: triphenylphosphine / dichloromethane

With triphenylphosphine; In dichloromethane; acetone;

DOI:10.1021/ja00316a028

Reference yield:

((C6H5)3PCH2C6H5)(1+)*FeCl4(1-)=((C6H5)3PCH2C6H5)FeCl4 (36021-10-0) + bis(benzyltriphenylphosphonium) bis(dithiooxalato-S,S')cuprate(II) (38999-75-6) → benzyltriphenylphosphonium bis(dithiooxalato-S,S')cuprate(III) (88326-23-2)

Guidance literature:

In dichloromethane; in presence of tetrabutylammonium chloride, in dark; Kinetics;

DOI:10.1021/ja00316a028

upstream raw materials:

benzyltriphenylphosphonium chloride

potassium 1,2-dithiooxalate

Downstream raw materials:

benzyltriphenylphosphonium bis(dithiooxalato-S,S')cuprate(III)

benzyltriphenylphosphonium (dithiooxalato-S,S')bis(triphenylphosphine)cuprate(I)