1(R)-1-<(tert-Butyldiphenylsilyl)oxy>-4(S)-cyclopent-2-ene

Base Information

Chemical Name:1(R)-1-<(tert-Butyldiphenylsilyl)oxy>-4(S)-cyclopent-2-ene
CAS No.:160057-21-6
Molecular Formula:C₂₉H₄₀N₂O₄Si
Molecular Weight:508.733
Hs Code.:

1(R)-1-<(tert-Butyldiphenylsilyl)oxy>-4(S)-<N-(N-Boc-L-alanyl)amino>cyclopent-2-ene

Synonyms:1(R)-1-<(tert-Butyldiphenylsilyl)oxy>-4(S)-cyclopent-2-ene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1(R)-1-<(tert-Butyldiphenylsilyl)oxy>-4(S)-cyclopent-2-ene

Chemical Property:

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Technology Process of 1(R)-1-<(tert-Butyldiphenylsilyl)oxy>-4(S)-cyclopent-2-ene

There total 6 articles about 1(R)-1-<(tert-Butyldiphenylsilyl)oxy>-4(S)-cyclopent-2-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 160167-77-1
cis-(1R,3S)-3-<(N-Boc-L-alanyl)amino>cyclopent-4-enol

: 160057-21-6
1(R)-1-<(tert-Butyldiphenylsilyl)oxy>-4(S)-cyclopent-2-ene

Guidance literature:: With 1H-imidazole; In dichloromethane; N,N-dimethyl-formamide; for 17h;
DOI:10.1021/jo00095a040

Reference yield:

: 15761-38-3
L-N-Boc-Ala

: 160057-21-6
1(R)-1-<(tert-Butyldiphenylsilyl)oxy>-4(S)-cyclopent-2-ene

Guidance literature:: Multi-step reaction with 5 steps

1: SOCl₂

2: 98 percent / NH₂OH*HCl, KOH / methanol

3: tetrabutylammonium periodate / methanol / 1 h

4: 89 percent / Mo(CO)6 / acetonitrile; H₂O / 3 h / Heating

5: 78 percent / imidazole / dimethylformamide; CH₂Cl₂ / 17 h

With 1H-imidazole; potassium hydroxide; thionyl chloride; hexacarbonyl molybdenum; hydroxylamine hydrochloride; tetrabutylammonium periodite; In methanol; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo00095a040

Reference yield:

: 28875-17-4
(S)-N-(tert-butoxycarbonyl)alanine methyl ester

: 160057-21-6
1(R)-1-<(tert-Butyldiphenylsilyl)oxy>-4(S)-cyclopent-2-ene

Guidance literature:: Multi-step reaction with 4 steps

1: 98 percent / NH₂OH*HCl, KOH / methanol

2: tetrabutylammonium periodate / methanol / 1 h

3: 89 percent / Mo(CO)6 / acetonitrile; H₂O / 3 h / Heating

4: 78 percent / imidazole / dimethylformamide; CH₂Cl₂ / 17 h

With 1H-imidazole; potassium hydroxide; hexacarbonyl molybdenum; hydroxylamine hydrochloride; tetrabutylammonium periodite; In methanol; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo00095a040