N-[1-(tert-butyldiphenylsilanyloxymethyl)-4-trityloxy-2-butenyl]-N-(1R)-(1-phenylethyl)amine

Base Information

Chemical Name:N-[1-(tert-butyldiphenylsilanyloxymethyl)-4-trityloxy-2-butenyl]-N-(1R)-(1-phenylethyl)amine
CAS No.:862107-63-9
Molecular Formula:C₄₈H₅₁NO₂Si
Molecular Weight:702.024
Hs Code.:

Synonyms:N-[1-(tert-butyldiphenylsilanyloxymethyl)-4-trityloxy-2-butenyl]-N-(1R)-(1-phenylethyl)amine

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Chemical Property of N-[1-(tert-butyldiphenylsilanyloxymethyl)-4-trityloxy-2-butenyl]-N-(1R)-(1-phenylethyl)amine

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Technology Process of N-[1-(tert-butyldiphenylsilanyloxymethyl)-4-trityloxy-2-butenyl]-N-(1R)-(1-phenylethyl)amine

There total 6 articles about N-[1-(tert-butyldiphenylsilanyloxymethyl)-4-trityloxy-2-butenyl]-N-(1R)-(1-phenylethyl)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 862107-62-8
N-[1-(tert-butyldiphenylsilanyloxymethyl)-4-trityloxy-2-butenyl]-N-(1R)-(1-phenylethyl)-hydroxylamine

: 862107-63-9
N-[1-(tert-butyldiphenylsilanyloxymethyl)-4-trityloxy-2-butenyl]-N-(1R)-(1-phenylethyl)amine

Guidance literature:: With samarium diiodide; In tetrahydrofuran; for 1.5h;
DOI:10.1021/ol050578j

Reference yield:

: 862107-60-6
C₂₆H₃₁NO₂Si

: 862107-63-9
N-[1-(tert-butyldiphenylsilanyloxymethyl)-4-trityloxy-2-butenyl]-N-(1R)-(1-phenylethyl)amine

Guidance literature:: Multi-step reaction with 3 steps

1: 84 percent / Zn(OSO₃CF₃); Et₃N / CH₂Cl₂ / 20 °C

2: 97 percent / H₂ / Lindlar catalyst / ethyl acetate / 3 h / 20 °C

3: 84 percent / SmI₂ / tetrahydrofuran / 1.5 h

With samarium diiodide; hydrogen; zinc trifluoromethanesulfonate; triethylamine; Lindlar's catalyst; In tetrahydrofuran; dichloromethane; ethyl acetate;
DOI:10.1021/ol050578j

Reference yield:

: N-[1-(tert-butyldiphenylsilanyloxymethyl)-4-trityloxy-2-butynyl]-N-(1R)-(1-phenylethyl)-hydroxylamine

: 862107-63-9
N-[1-(tert-butyldiphenylsilanyloxymethyl)-4-trityloxy-2-butenyl]-N-(1R)-(1-phenylethyl)amine

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / H₂ / Lindlar catalyst / ethyl acetate / 3 h / 20 °C

2: 84 percent / SmI₂ / tetrahydrofuran / 1.5 h

With samarium diiodide; hydrogen; Lindlar's catalyst; In tetrahydrofuran; ethyl acetate;
DOI:10.1021/ol050578j