5-(4-(10H-phenoxazin-10-yl)phenyl)thiophene-2-carbaldehyde

Base Information

• Chemical Name: 5-(4-(10H-phenoxazin-10-yl)phenyl)thiophene-2-carbaldehyde
• CAS No.: 1507401-59-3
• Molecular Formula: C₂₃H₁₅NO₂S
• Molecular Weight: 369.444
• Mol file: 1507401-59-3.mol

Synonyms:5-(4-(10H-phenoxazin-10-yl)phenyl)thiophene-2-carbaldehyde

Chemical Property of 5-(4-(10H-phenoxazin-10-yl)phenyl)thiophene-2-carbaldehyde

Chemical Property:

Purity/Quality:

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Technology Process of 5-(4-(10H-phenoxazin-10-yl)phenyl)thiophene-2-carbaldehyde

There total 6 articles about 5-(4-(10H-phenoxazin-10-yl)phenyl)thiophene-2-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

10-(4-Bromophenyl)-10H-phenoxazine (71041-21-9) + (5-formylthiophen-2-yl)boronic acid → 5-(4-(10H-phenoxazin-10-yl)phenyl)thiophene-2-carbaldehyde (1507401-59-3)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium acetate; In tetrahydrofuran; at 70 ℃; for 24h; Inert atmosphere;

DOI:10.1016/j.dyepig.2013.09.039

Reference yield: 31.0%

1,4-bromoiodobenzene (589-87-7) → 5-(4-(10H-phenoxazin-10-yl)phenyl)thiophene-2-carbaldehyde (1507401-59-3) + bis[4-(3,6-di-tert-butylcarbazole)phenyl] sulfone (1396165-20-0)

Guidance literature:

With 18-crown-6 ether; copper; potassium carbonate; In N,N-dimethyl-formamide; for 48h; Inert atmosphere; Reflux;

DOI:10.1021/ja5040073

Reference yield: 31.0%

1,4-bromoiodobenzene (589-87-7) + (R,Z)-4,4,5,5-tetramethyl-2-(2-methylhex-4-en-3-yl)-1,3,2-dioxaborolane → 5-(4-(10H-phenoxazin-10-yl)phenyl)thiophene-2-carbaldehyde (1507401-59-3) + bis[4-(3,6-di-tert-butylcarbazole)phenyl] sulfone (1396165-20-0) + 4-bromo-N-(4-bromophenyl)-N-(4-((triisopropylsilyl)ethynyl)phenyl)aniline (1564287-27-9)

Guidance literature:

With 18-crown-6 ether; copper; potassium carbonate; In N,N-dimethyl-formamide; for 48h; Inert atmosphere; Reflux;

DOI:10.1021/ja5040073

upstream raw materials:

1,4-bromoiodobenzene

10-(4-Bromophenyl)-10H-phenoxazine

Downstream raw materials:

C₂₆H₁₆N₂O₃S