2(C₆H₅)3P2Rh⁽²⁺⁾2C₂B₉H₁₁^(2-)=[((C₆H₅)3P)RhC₂B₉H₁₁]2

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Chemical Name:2(C₆H₅)3P*2Rh⁽²⁺⁾*2C₂B₉H₁₁^(2-)=[((C₆H₅)3P)RhC₂B₉H₁₁]2
CAS No.:68914-09-0
Molecular Formula:C₄₀H₅₂B₁₈P₂Rh₂
Molecular Weight:995.209
Hs Code.:

2(C<sub>6</sub>H<sub>5</sub>)3P*2Rh<sup>(2+)</sup>*2C<sub>2</sub>B<sub>9</sub>H<sub>11</sub><sup>(2-)</sup>=[((C<sub>6</sub>H<sub>5</sub>)3P)RhC<sub>2</sub>B<sub>9</sub>H<sub>11</sub>]2

Synonyms:2(C₆H₅)3P*2Rh⁽²⁺⁾*2C₂B₉H₁₁^(2-)=[((C₆H₅)3P)RhC₂B₉H₁₁]2

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Chemical Property of 2(C₆H₅)3P*2Rh⁽²⁺⁾*2C₂B₉H₁₁^(2-)=[((C₆H₅)3P)RhC₂B₉H₁₁]2

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Technology Process of 2(C₆H₅)3P*2Rh⁽²⁺⁾*2C₂B₉H₁₁^(2-)=[((C₆H₅)3P)RhC₂B₉H₁₁]2

There total 5 articles about 2(C₆H₅)3P*2Rh⁽²⁺⁾*2C₂B₉H₁₁^(2-)=[((C₆H₅)3P)RhC₂B₉H₁₁]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 94234-91-0
Tl⁽¹⁺⁾*C₂B₉H₁₂^(1-)=Tl(C₂B₉H₁₂)

: 68914-09-0
1,1'-bis(triphenylphosphine)(3,4,4',5'-tetracarba-1,1'dirhoda((12v)(Ih-(1551)-Δ20-closo)-(1:1')-(1,2-di-μH-2',1')(12v)(Ih-(1551)-Δ20-closo)tetracosaborane))

Guidance literature:: With triphenylphosphine; In tetrahydrofuran; dichloromethane; dissolution of Rh-complex and PPh3 in CH2Cl2 (under N2), stirring for 10 min, removal of solvent, addn. of carborane and THF to the residue, refluxing for 3 days;; cooling to room temp., filtn. through Celite, evapn. of solvent, purification of the residue by column chromy. (silica gel) via elution wiht benzene-heptane;;
DOI:10.1021/ja00290a031

Reference yield: 74.0%

: 53687-46-0
closo-3,3-(PPh₃)2-3-H-3,1,2-RhC₂B₉H₁₁

: 19287-45-7
diborane

: 68914-09-0
2(C₆H₅)3P*2Rh⁽²⁺⁾*2C₂B₉H₁₁^(2-)=[((C₆H₅)3P)RhC₂B₉H₁₁]2

: 2049-55-0
triphenylphosphine borane

Guidance literature:: In benzene; educt slurried in benzene, B2H6 bubbled through soln. for 24 h; purged with Ar, evapd. in vac., chromd. (SiO2, benzene/heptane), concd.in vac., filtered, dried in vac.;

Reference yield: 22.0%

: 53687-46-0
closo-3,3-(PPh₃)2-3-H-3,1,2-RhC₂B₉H₁₁

: 10294-33-4
boron tribromide

: 3426-98-0
((C₆H₅)3P)BBr₃

: 68914-09-0
2(C₆H₅)3P*2Rh⁽²⁺⁾*2C₂B₉H₁₁^(2-)=[((C₆H₅)3P)RhC₂B₉H₁₁]2

: 87226-21-9
[HP(C₆H₅)3]⁽¹⁺⁾*[((C₆H₅)3P)Br₂RhC₂B₉H₁₁]^(1-)*1.5C₆H₆=[HP(C₆H₅)3][((C₆H₅)3P)Br₂RhC₂B₉H₁₁]*1.5C₆H₆

Guidance literature:: With benzene; In benzene; under N2 or Ar, Rh complex slurried in benzene, BBr3 distd. onto frozenreact. mixt., thawed to ambient temp., stirred for 48 h; concd. in vac., filtered, chromd. (Florisil, benzene), heptane added, concd. in vac., recrystd.; elem. anal.;