[5-¹⁵N]-5-((4-bromophenyl)azo)-2-bromo-4-imidazolecarboxylic acid

Base Information

• Chemical Name: [5-¹⁵N]-5-((4-bromophenyl)azo)-2-bromo-4-imidazolecarboxylic acid
• CAS No.: 129756-80-5
• Molecular Formula: C₁₀H₆Br₂N₄O₂
• Molecular Weight: 374.985
• Mol file: 129756-80-5.mol

Synonyms:[5-¹⁵N]-5-((4-bromophenyl)azo)-2-bromo-4-imidazolecarboxylic acid

Chemical Property of [5-¹⁵N]-5-((4-bromophenyl)azo)-2-bromo-4-imidazolecarboxylic acid

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of [5-¹⁵N]-5-((4-bromophenyl)azo)-2-bromo-4-imidazolecarboxylic acid

There total 3 articles about [5-¹⁵N]-5-((4-bromophenyl)azo)-2-bromo-4-imidazolecarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-bromo-aniline (106-40-1) + 2-bromo-1H-imidazole-4,5-dicarboxylic acid (773099-17-5) → [5-15N]-5-((4-bromophenyl)azo)-2-bromo-4-imidazolecarboxylic acid (129756-80-5)

Guidance literature:

4-bromo-aniline; With sodium ⁽¹⁵⁾N-nitrite; In hydrogenchloride; water; at 0 ℃; for 0.333333h;

2-bromo-1H-imidazole-4,5-dicarboxylic acid; With sodium carbonate; In water; for 2h;

DOI:10.1021/jo982372k

Reference yield:

4-bromo-aniline (106-40-1) + diethyl 2-bromo-1H-imidazole-4,5-dicarboxylate (129756-78-1) → [5-15N]-5-((4-bromophenyl)azo)-2-bromo-4-imidazolecarboxylic acid (129756-80-5)

Guidance literature:

diethyl 2-bromo-1H-imidazole-4,5-dicarboxylate; With sodium carbonate; In water; at 100 ℃; for 36h;

4-bromo-aniline; With sodium ⁽¹⁵⁾N-nitrite; In water; for 0.0833333h; Cooling;

DOI:10.1002/jlcr.3051

Reference yield:

C5BrN2O4(3-)*3Na(1+) (129756-79-2) + 4-bromo-aniline (106-40-1) → [5-15N]-5-((4-bromophenyl)azo)-2-bromo-4-imidazolecarboxylic acid (129756-80-5)

Guidance literature:

With sodium ⁽¹⁵⁾N-nitrite; hydrogen cation; Yield given. Multistep reaction;

DOI:10.1021/ja00178a056

upstream raw materials:

C₅BrN₂O₄^(3-)*3Na⁽¹⁺⁾

4-bromo-aniline

2-bromo-1H-imidazole-4,5-dicarboxylic acid

diethyl 2-bromo-1H-imidazole-4,5-dicarboxylate

Downstream raw materials:

C₁₀H₇Br₂N₄⁽¹⁵⁾NO