5-O-mycaminosylprotylonolide

Base Information

Chemical Name:5-O-mycaminosylprotylonolide
CAS No.:81661-90-7
Molecular Formula:C₃₁H₅₃NO₈
Molecular Weight:567.764
Hs Code.:
Mol file:81661-90-7.mol

Synonyms:5-O-mycaminosyl tylactone;(11Z,13E)-6-[4-(dimethylamino)-3,5-dihydroxy-6-methyloxan-2-yl]oxy-7,16-diethyl-4-hydroxy-5,9,13,15-tetramethyl-1-oxacyclohexadeca-11,13-diene-2,10-dione;mycaminosyl tylactone;5-O-Mycaminosylprotylonolide;5-Mcpt;5-O-beta-D-mycaminosyltylactone;

Suppliers and Price of 5-O-mycaminosylprotylonolide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 5-O-mycaminosylprotylonolide

Chemical Property:

Vapor Pressure:1.69E-24mmHg at 25°C
Boiling Point:728.4°C at 760 mmHg
Flash Point:394.3°C
PSA：125.76000
Density:1.13g/cm³
LogP:3.25100

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 5-O-mycaminosylprotylonolide

There total 6 articles about 5-O-mycaminosylprotylonolide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 81661-89-4
20,23-dideoxy-20,23-diiodo-5-O-mycaminosylrelonolide

: 81661-90-7
5-O-mycaminosylprotylonolide

Guidance literature:: With sodium cyanoborohydride; In N,N,N,N,N,N-hexamethylphosphoric triamide; at 50 ℃; for 8.5h;
DOI:10.1248/cpb.30.97

Reference yield:

: 1401-69-0
15-[[(6-deoxy-2,6-di-O-methyl-β-D-allopyranosyl)-oxy]methyl]-6-[[3,6-dideoxy-4-O-(2,6-dideoxy-3-C-methyl-α-L-ribo-hexapyranosyl)-3-(dimethylamino)-β-D-glucopyranosyl]oxy]-16-ethyl-4-hydroxy-5,9,13-trimethyl-2,10-oxo-oxocyclo-hexadeca-11,13-diene-7...

: 81661-90-7
5-O-mycaminosylprotylonolide

Guidance literature:: Multi-step reaction with 5 steps

1: 0.2N HCl / 4 h

2: 6.5 g / 0.5N HCl / 20 h / 90 °C

3: 3.0 g / NaBH₄, 0.2 M phosphate buffer / methanol / 19 h / Ambient temperature

4: 2.1 g / I₂, triphenylphosphine / dimethylformamide / 2 h / Ambient temperature

5: 1.2 g / NaBH₃CN / hexamethylphosphoric acid triamide / 8.5 h / 50 °C

With hydrogenchloride; sodium tetrahydroborate; phosphate buffer; iodine; sodium cyanoborohydride; triphenylphosphine; In methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide;
DOI:10.1248/cpb.30.97

Reference yield:

: 66767-27-9
5-O-mycaminosylrelonolide

: 81661-90-7
5-O-mycaminosylprotylonolide

Guidance literature:: Multi-step reaction with 2 steps

1: 2.1 g / I₂, triphenylphosphine / dimethylformamide / 2 h / Ambient temperature

2: 1.2 g / NaBH₃CN / hexamethylphosphoric acid triamide / 8.5 h / 50 °C

With iodine; sodium cyanoborohydride; triphenylphosphine; In N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide;
DOI:10.1248/cpb.30.97