2-(ethylthio)methyl-1-triphenylphosphoranylideneaminobenzene

Base Information

• Chemical Name: 2-(ethylthio)methyl-1-triphenylphosphoranylideneaminobenzene
• CAS No.: 1416169-59-9
• Molecular Formula: C₂₇H₂₆NPS
• Molecular Weight: 427.55
• Mol file: 1416169-59-9.mol

Synonyms:2-(ethylthio)methyl-1-triphenylphosphoranylideneaminobenzene

Chemical Property of 2-(ethylthio)methyl-1-triphenylphosphoranylideneaminobenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(ethylthio)methyl-1-triphenylphosphoranylideneaminobenzene

There total 2 articles about 2-(ethylthio)methyl-1-triphenylphosphoranylideneaminobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

1-azido-2-(ethylthio)methylbenzene (1416169-58-8) + triphenylphosphine (603-35-0) → 2-(ethylthio)methyl-1-triphenylphosphoranylideneaminobenzene (1416169-59-9)

Guidance literature:

In diethyl ether; at 20 ℃; for 16h; Inert atmosphere;

DOI:10.1039/c2ob27010b

Reference yield:

2-azidobenzyl iodide (217975-00-3) → 2-(ethylthio)methyl-1-triphenylphosphoranylideneaminobenzene (1416169-59-9)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium hydroxide / dimethyl sulfoxide / 2.33 h / 20 °C

2: diethyl ether / 16 h / 20 °C / Inert atmosphere

With potassium hydroxide; In diethyl ether; dimethyl sulfoxide; 2: |Staudinger Azide Reduction;

DOI:10.1039/c2ob27010b

Reference yield:

2-(ethylthio)methyl-1-triphenylphosphoranylideneaminobenzene (1416169-59-9) + diphenyl ketene (525-06-4) → C23H21NS (1416169-60-2)

Guidance literature:

In o-xylene; at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1039/c2ob27010b

upstream raw materials:

1-azido-2-(ethylthio)methylbenzene

triphenylphosphine

2-azidobenzyl iodide

Downstream raw materials:

4-ethylthio-3,3-diphenyl-3,4-dihydroquinoline

C₂₃H₂₁NS