(S(Fc))-(diphenylthioxophosphanyl)[2-(dibenzo-thioxo-1H-1λ5-phosphol-1-yl)ferrocenyl]methane

Base Information

• Chemical Name: (S(Fc))-(diphenylthioxophosphanyl)[2-(dibenzo-thioxo-1H-1λ5-phosphol-1-yl)ferrocenyl]methane
• CAS No.: 955375-13-0
• Molecular Formula: C₃₅H₂₈FeP₂S₂
• Molecular Weight: 630.534
• Mol file: 955375-13-0.mol

Synonyms:(S(Fc))-(diphenylthioxophosphanyl)[2-(dibenzo-thioxo-1H-1λ5-phosphol-1-yl)ferrocenyl]methane

Chemical Property of (S(Fc))-(diphenylthioxophosphanyl)[2-(dibenzo-thioxo-1H-1λ5-phosphol-1-yl)ferrocenyl]methane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (S(Fc))-(diphenylthioxophosphanyl)[2-(dibenzo-thioxo-1H-1λ5-phosphol-1-yl)ferrocenyl]methane

There total 1 articles about (S(Fc))-(diphenylthioxophosphanyl)[2-(dibenzo-thioxo-1H-1λ5-phosphol-1-yl)ferrocenyl]methane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

sulfur (10544-50-0) + (S(Fc))-acetoxy[2-(dibenzo-1-thioxo-1H-1λ5-phosphol-1-yl)ferrocenyl]methane (955375-11-8) + diphenylphosphane (829-85-6) → (S(Fc))-(diphenylthioxophosphanyl)[2-(dibenzo-thioxo-1H-1λ5-phosphol-1-yl)ferrocenyl]methane (955375-13-0)

Guidance literature:

In dichloromethane; toluene; Ph2PH (2.5 equiv.) added to soln. of Fe compd. in toluene at room temp.,refluxed for 36 h, concd., dissolved (CH2Cl2), sulfur (5 equiv.) added, stirred overnight; concd., chromd. (SiO2, pentane/Et2O=8:2, v/v);

DOI:10.1002/ejic.200600771

Reference yield: 94.0%

(S(Fc))-(diphenylthioxophosphanyl)[2-(dibenzo-thioxo-1H-1λ5-phosphol-1-yl)ferrocenyl]methane (955375-13-0) → (S(Fc))-(diphenylphosphanyl)[2-(dibenzo-1H-1λ5-phosphol-1-yl)ferrocenyl]methane (916904-58-0)

Guidance literature:

With P(NMe₂)3; In toluene; P(NMe2)3 (4 equiv.) added to soln. of Fe compd. in toluene at room temp., refluxed for 24 h; concd., chromd. (Al2O3, pentane; pentane/Et2O=9:1, v/v);

DOI:10.1002/ejic.200600771

Reference yield:

(S(Fc))-(diphenylthioxophosphanyl)[2-(dibenzo-thioxo-1H-1λ5-phosphol-1-yl)ferrocenyl]methane (955375-13-0) → (SFc)-diphenyl[2-(9-thioxo-9λ(5)-phosphafluoren-9-yl)ferrocenylmethyl]phosphine

Guidance literature:

With P(NMe₂)3; In toluene; refluxing;

DOI:10.1107/S0108270106010833

upstream raw materials:

sulfur

(S(Fc))-acetoxy[2-(dibenzo-1-thioxo-1H-1λ5-phosphol-1-yl)ferrocenyl]methane

diphenylphosphane

Downstream raw materials:

(S(Fc))-(diphenylphosphanyl)[2-(dibenzo-1H-1λ5-phosphol-1-yl)ferrocenyl]methane