Technology Process of methyl 2,3,4-tri-O-benzyl-6-O-methyl-α-D-glucopyranoside
There total 18 articles about methyl 2,3,4-tri-O-benzyl-6-O-methyl-α-D-glucopyranoside which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
methyl 2,3,4-tri-O-benzyl-D-glucopyranoside;
With
sodium hydride;
In
N,N-dimethyl-formamide;
at 0 ℃;
for 1h;
methyl iodide;
In
N,N-dimethyl-formamide;
at 0 - 20 ℃;
for 3h;
DOI:10.1002/chem.201603748
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: camphor-10-sulfonic acid / acetonitrile / 0.33 h / 80 °C
2.1: sodium hydride / N,N-dimethyl-formamide; paraffin oil / 1 h / 0 - 5 °C
2.2: 24 h / 0 - 20 °C
3.1: lithium aluminium tetrahydride; aluminum (III) chloride / diethyl ether; dichloromethane / 2 h / 50 °C
4.1: sodium hydride / N,N-dimethyl-formamide; paraffin oil / 1 h / 0 °C
4.2: 24 h / 0 - 20 °C
With
aluminum (III) chloride; lithium aluminium tetrahydride; camphor-10-sulfonic acid; sodium hydride;
In
diethyl ether; dichloromethane; N,N-dimethyl-formamide; acetonitrile; paraffin oil;
DOI:10.1002/ejoc.201100861
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: camphor-10-sulfonic acid / acetonitrile / 0.33 h / 80 °C
2.1: sodium hydride / N,N-dimethyl-formamide; paraffin oil / 1 h / 0 - 5 °C
2.2: 24 h / 0 - 20 °C
3.1: lithium aluminium tetrahydride; aluminum (III) chloride / diethyl ether; dichloromethane / 2 h / 50 °C
4.1: sodium hydride / N,N-dimethyl-formamide; paraffin oil / 1 h / 0 °C
4.2: 24 h / 0 - 20 °C
With
aluminum (III) chloride; lithium aluminium tetrahydride; camphor-10-sulfonic acid; sodium hydride;
In
diethyl ether; dichloromethane; N,N-dimethyl-formamide; acetonitrile; paraffin oil;
DOI:10.1002/ejoc.201100861
