2,3,4,6-tetra-O-benzyl-D-glucopyranose trichloroacetimidate

Base Information

• Chemical Name: 2,3,4,6-tetra-O-benzyl-D-glucopyranose trichloroacetimidate
• CAS No.: 132201-75-3
• Molecular Formula: C₃₆H₃₆Cl₃NO₆
• Molecular Weight: 685.044
• Mol file: 132201-75-3.mol

Synonyms:2,3,4,6-tetra-O-benzyl-D-glucopyranose trichloroacetimidate

Chemical Property of 2,3,4,6-tetra-O-benzyl-D-glucopyranose trichloroacetimidate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,3,4,6-tetra-O-benzyl-D-glucopyranose trichloroacetimidate

There total 40 articles about 2,3,4,6-tetra-O-benzyl-D-glucopyranose trichloroacetimidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2,3,4,6-Tetra-O-benzyl-D-glucopyranose (4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5,4132-28-9) + trichloroacetonitrile (545-06-2) → 2,3,4,6-tetra-O-benzyl-D-glucopyranose trichloroacetimidate (132201-75-3)

Guidance literature:

With potassium carbonate; In dichloromethane; at 20 ℃; for 23h;

DOI:10.1016/S0008-6215(99)00131-7

Reference yield: 100.0%

2,3,4,6-tetra-O-benzyl-D-mannopyranose (4132-28-9,4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5) + trichloroacetonitrile (545-06-2) → 2,3,4,6-tetra-O-benzyl-α-D-mannopyranosyl trichloroacetimidate (74808-09-6,90357-89-4,90358-01-3,103368-01-0,103368-04-3,103368-06-5,104048-30-8,104048-33-1,114743-70-3,132201-75-3,132748-02-8,83441-60-5)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 20 ℃; for 18h;

DOI:10.1055/s-0029-1218772

Reference yield: 99.0%

2,3,4,6-tetra-O-benzyl-D-glucopyranose (6564-72-3) + trichloroacetonitrile (545-06-2) → 2,3,4,6-tetra-O-benzyl-D-glucopyranose trichloroacetimidate (132201-75-3)

Guidance literature:

polystyrene supported organic base (PS-DBU); In dichloromethane; at 20 ℃; for 3.5h;

DOI:10.1016/j.tetlet.2005.02.055

upstream raw materials:

2,3,4,6-tetra-O-benzyl-D-galactopyranose

trichloroacetonitrile

2-propenyl 2,3,4,6-tetra-O-benzyl-α-D-glactopyranoside

benzyl bromide

Downstream raw materials:

2,3,4,6-tetra-O-benzyl-D-glucopyranosyl-(1?1)-2,3,4,6-tetra-O-benzyl-D-glucopyranoside

1-((2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-(1->4)-(2,3,6-tri-O-benzoyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-α-D-glucopyranosyl)-2-propene

allyl 2,6-di-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-β-D-galactopyranoside

allyl 2,6-di-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-α-D-galactopyranoside