3,3,4,4,5,5,6,6,6-Nonafluorohexyl methacrylate

Base Information

• Chemical Name: 3,3,4,4,5,5,6,6,6-Nonafluorohexyl methacrylate
• CAS No.: 1799-84-4
• Molecular Formula: C10H9F9O2
• Molecular Weight: 332.166
• Hs Code.: 29161290
• European Community (EC) Number: 217-287-5
• DSSTox Substance ID: DTXSID8061979
• Nikkaji Number: J199.622C
• Wikidata: Q72500446
• Mol file: 1799-84-4.mol

Synonyms:1799-84-4;3,3,4,4,5,5,6,6,6-Nonafluorohexyl methacrylate;2-(Perfluorobutyl)ethyl methacrylate;2-(nonafluorobutyl)ethyl methacrylate;1h,1h,2h,2h-perfluorohexyl methacrylate;3,3,4,4,5,5,6,6,6-nonafluorohexyl 2-methylprop-2-enoate;1H,1H,2H,2H-Nonafluorohexyl Methacrylate;C10H9F9O2;EINECS 217-287-5;MFCD00236094;Methacrylic acid, 3,3,4,4,5,5,6,6,6-nonafluorohexyl ester;2-Propenoic acid, 2-methyl-, 3,3,4,4,5,5,6,6,6-nonafluorohexyl ester;SCHEMBL156101;DTXSID8061979;2-(perfluorobutyl)ethylmethacrylate;C10-H9-F9-O2;FD2034;AKOS005063623;DS-9218;SY018481;CS-0158069;FT-0608882;N1014;N1143;3,3,4,4,5,5,6,6,6-Nonafluorohexylmethacrylate;J-011486;Methacrylic Acid 1H,1H,2H,2H-Nonafluorohexyl Ester;2-(Perfluorobutyl)ethyl methacrylate inhibited with 70 ppm BHT;Methacrylic Acid 3,3,4,4,5,5,6,6,6-Nonafluorohexyl Ester;1H,1H,2H,2H-Nonafluorohexyl Methacrylate (stabilized with MEHQ);2-Methylpropenoic acid 3,3,4,4,5,5,6,6,6-nonafluorohexyl ester

Chemical Property of 3,3,4,4,5,5,6,6,6-Nonafluorohexyl methacrylate

Chemical Property:

• Vapor Pressure: 0.681mmHg at 25°C
• Refractive Index: 1.353
• Boiling Point: 185.9°Cat760mmHg
• Flash Point: 64.8°C
• PSA: 26.30000
• Density: 1.377g/cm³
• LogP: 3.96400
• Storage Temp.: Keep Cold
• Water Solubility.: Insoluble in water
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 7
• Exact Mass: 332.04588298
• Heavy Atom Count: 21
• Complexity: 411

Purity/Quality:

99% ^*data from raw suppliers

PerfluorobutylethylMethacrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xi
• Hazard Codes: F,Xi
• Statements: 36/37/38-36/38
• Safety Statements: 26-36-36/37/39-15

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OCCC(C(C(C(F)(F)F)(F)F)(F)F)(F)F
• Uses: Perfluorobutylethyl Methacrylate was used to prepare fluorinated latexes by polymerization of miniemulsions as fluorinated monomers.Along with Perfluorodecylethyl Methacrylate (P286590), Perfluorobutylethyl Methacrylate was one of the pollutants from Great Lakes studied.

Technology Process of 3,3,4,4,5,5,6,6,6-Nonafluorohexyl methacrylate

There total 3 articles about 3,3,4,4,5,5,6,6,6-Nonafluorohexyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

methacryloyl anhydride (760-93-0) + 1H,1H,2H,2H-nonafluoro-1-hexanol (2043-47-2) → 3,3,4,4,5,5,6,6,6,-nonafluorohexyl methacrylate (1799-84-4)

Guidance literature:

With dmap; triethylamine; In dichloromethane; 1,1,2-Trichloro-1,2,2-trifluoroethane; at 30 ℃; for 18h;

DOI:10.1016/S0022-1139(96)03569-5

Reference yield:

→ 3,3,4,4,5,5,6,6,6,-nonafluorohexyl methacrylate (1799-84-4)

Guidance literature:

entspr. Methylester, Umesterung;

Reference yield:

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + 1H,1H,2H,2H-nonafluoro-1-hexanol (2043-47-2) → 3,3,4,4,5,5,6,6,6,-nonafluorohexyl methacrylate (1799-84-4)

Guidance literature:

With triethylamine; benzenesulfonyl chloride; Sumilizer GM; In dichloromethane; at 20 - 40 ℃; for 1h;

upstream raw materials:

methacryloyl anhydride

1H,1H,2H,2H-nonafluoro-1-hexanol

poly(methacrylic acid)

Refernces

• 1、 Krupers, Maarten J.,Moeller, Martin. "Synthesis and characterization of semifluorinated polymers via group transfer polymerization". . p. 119 - 124. Retrieved 2007/10/03.