diphenyl(phenylthio)bismuthine

Base Information

Chemical Name:diphenyl(phenylthio)bismuthine
CAS No.:115419-47-1
Molecular Formula:C₁₈H₁₅BiS
Molecular Weight:472.364
Hs Code.:

Synonyms:diphenyl(phenylthio)bismuthine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of diphenyl(phenylthio)bismuthine

Chemical Property:

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Technology Process of diphenyl(phenylthio)bismuthine

There total 5 articles about diphenyl(phenylthio)bismuthine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 5153-28-6
diphenylbismuth(III) chloride

: 108-98-5
thiophenol

: 115419-47-1
diphenyl(phenylthio)bismuthine

Guidance literature:: In diethyl ether; several hours;
DOI:10.1021/ja01150a134

Reference yield: 75.0%

: 39248-62-9
diphenylbismuthanyl bromide

: 108-98-5
thiophenol

: 115419-47-1
diphenyl(phenylthio)bismuthine

Guidance literature:: With n-butyllithium; In diethyl ether; hexane; n-butyllithium in hexane slowly added to soln. ligand in ether at -78°C, stirred for 1 h, slowly warmed to room temp. over 1 h, Bi-compound added at 0°C, stirred for 2 h at room temp., H2O added; organic layer sepd., washed with satd. aq. soln. of NH4Cl and satd. aq. NaCl soln., dried over MgSO4, passed through pad of Celite, solvent removed under reduced pressure, recrystd. from CHCl3/hexane;
DOI:10.1021/ja8092899

Reference yield: 46.0%

: 7065-21-6
tetraphenyldibismuthine

: 882-33-7
diphenyldisulfane

: 115419-47-1
diphenyl(phenylthio)bismuthine

Guidance literature:: In toluene; addn. of Bi2Ph4 to soln. of S2Ph2 (room temp.), after 45 min filtration; pptn. on addn. of n-heptane, sepn. (filtration), drying (vac.); elem. anal.;