diphenyl(phenylthio)bismuthine

Base Information

• Chemical Name: diphenyl(phenylthio)bismuthine
• CAS No.: 115419-47-1
• Molecular Formula: C₁₈H₁₅BiS
• Molecular Weight: 472.364
• Mol file: 115419-47-1.mol

Synonyms:diphenyl(phenylthio)bismuthine

Chemical Property of diphenyl(phenylthio)bismuthine

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of diphenyl(phenylthio)bismuthine

There total 5 articles about diphenyl(phenylthio)bismuthine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

diphenylbismuth(III) chloride (5153-28-6) + thiophenol (108-98-5) → diphenyl(phenylthio)bismuthine (115419-47-1)

Guidance literature:

In diethyl ether; several hours;

DOI:10.1021/ja01150a134

Reference yield: 75.0%

diphenylbismuthanyl bromide (39248-62-9) + thiophenol (108-98-5) → diphenyl(phenylthio)bismuthine (115419-47-1)

Guidance literature:

With n-butyllithium; In diethyl ether; hexane; n-butyllithium in hexane slowly added to soln. ligand in ether at -78°C, stirred for 1 h, slowly warmed to room temp. over 1 h, Bi-compound added at 0°C, stirred for 2 h at room temp., H2O added; organic layer sepd., washed with satd. aq. soln. of NH4Cl and satd. aq. NaCl soln., dried over MgSO4, passed through pad of Celite, solvent removed under reduced pressure, recrystd. from CHCl3/hexane;

DOI:10.1021/ja8092899

Reference yield: 46.0%

tetraphenyldibismuthine (7065-21-6) + diphenyldisulfane (882-33-7) → diphenyl(phenylthio)bismuthine (115419-47-1)

Guidance literature:

In toluene; addn. of Bi2Ph4 to soln. of S2Ph2 (room temp.), after 45 min filtration; pptn. on addn. of n-heptane, sepn. (filtration), drying (vac.); elem. anal.;

upstream raw materials:

diphenylbismuth(III) chloride

thiophenol

tetraphenyldibismuthine

diphenyldisulfane

Downstream raw materials:

diphenyl[2-(phenylthio)phenyl]bismuthane

Refernces

• 1、 Kayahara, Eiichi,Yamago, Shigeru. "Development of an arylthiobismuthine cocatalyst in organobismuthine- mediated living radical polymerization: Applications for synthesis of ultrahigh molecular weight polystyrenes and polyacrylates". . p. 2508 - 2513. Retrieved 2009/07/26.