endo-9-benzyl-7,8-diaza-1-methyl-9-methyl-d3-6-phenyltricyclo<4.2.1.0^2,5>non-7-ene

Base Information

• Chemical Name: endo-9-benzyl-7,8-diaza-1-methyl-9-methyl-d3-6-phenyltricyclo<4.2.1.0^2,5>non-7-ene
• CAS No.: 74971-32-7
• Molecular Formula: C₂₂H₂₄N₂
• Molecular Weight: 319.422

Synonyms:endo-9-benzyl-7,8-diaza-1-methyl-9-methyl-d3-6-phenyltricyclo<4.2.1.0^2,5>non-7-ene

Chemical Property of endo-9-benzyl-7,8-diaza-1-methyl-9-methyl-d3-6-phenyltricyclo<4.2.1.0^2,5>non-7-ene

Chemical Property:

Purity/Quality:

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Technology Process of endo-9-benzyl-7,8-diaza-1-methyl-9-methyl-d3-6-phenyltricyclo<4.2.1.0^2,5>non-7-ene

There total 6 articles about endo-9-benzyl-7,8-diaza-1-methyl-9-methyl-d3-6-phenyltricyclo<4.2.1.0^2,5>non-7-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

endo-9-benzyl-7,8-diaza-1-methyl-9-methyl-d3-6-phenyltricyclo<4.2.1.02,5>nona-3,7-diene (74971-27-0) → endo-9-benzyl-7,8-diaza-1-methyl-9-methyl-d3-6-phenyltricyclo<4.2.1.02,5>non-7-ene (74971-32-7)

Guidance literature:

With potassium diazodicarboxylate; acetic acid; In methanol; for 0.5h;

DOI:10.1021/ja00533a018

Reference yield:

2-benzyl-1-phenylbutane-1,3-dione (28918-08-3) → endo-9-benzyl-7,8-diaza-1-methyl-9-methyl-d3-6-phenyltricyclo<4.2.1.02,5>non-7-ene (74971-32-7)

Guidance literature:

Multi-step reaction with 4 steps

1: 96 percent / sodium hydride / dimethylsulfoxide

2: 64 percent / hydrazine hydrate / CCl₄ / 1 h / Heating

3: 34 percent / ceric ammonium nitrate / acetone / 0.5 h / -20 °C

4: 93 percent / dipotassium azodicarboxylate, acetic acid / methanol / 0.5 h

With ammonium cerium(IV) nitrate; potassium diazodicarboxylate; sodium hydride; hydrazine hydrate; acetic acid; In methanol; tetrachloromethane; dimethyl sulfoxide; acetone;

DOI:10.1021/ja00533a018

Reference yield:

benzyl bromide (100-39-0) → endo-9-benzyl-7,8-diaza-1-methyl-9-methyl-d3-6-phenyltricyclo<4.2.1.02,5>non-7-ene (74971-32-7)

Guidance literature:

Multi-step reaction with 5 steps

1: 86.4 percent / sodium hydride / dimethylsulfoxide

2: 96 percent / sodium hydride / dimethylsulfoxide

3: 64 percent / hydrazine hydrate / CCl₄ / 1 h / Heating

4: 34 percent / ceric ammonium nitrate / acetone / 0.5 h / -20 °C

5: 93 percent / dipotassium azodicarboxylate, acetic acid / methanol / 0.5 h

With ammonium cerium(IV) nitrate; potassium diazodicarboxylate; sodium hydride; hydrazine hydrate; acetic acid; In methanol; tetrachloromethane; dimethyl sulfoxide; acetone;

DOI:10.1021/ja00533a018

upstream raw materials:

endo-9-benzyl-7,8-diaza-1-methyl-9-methyl-d3-6-phenyltricyclo<4.2.1.0^2,5>nona-3,7-diene

2-benzyl-1-phenylbutane-1,3-dione

benzyl bromide

C₁₈H₁₅⁽²⁾H₃O₂

Downstream raw materials:

anti-3-benzyl-2-methyl-3-methyl-d3-4-phenyltricyclo<3.2.0.0^2,4>heptane

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