2-((2,6-dibenzhydryl-4-methylphenylimino)methyl)-6-tert-butyl-4-methylphenol

Base Information

• Chemical Name: 2-((2,6-dibenzhydryl-4-methylphenylimino)methyl)-6-tert-butyl-4-methylphenol
• CAS No.: 1392281-16-1
• Molecular Formula: C₄₅H₄₃NO
• Molecular Weight: 613.843
• Mol file: 1392281-16-1.mol

Synonyms:2-((2,6-dibenzhydryl-4-methylphenylimino)methyl)-6-tert-butyl-4-methylphenol

Chemical Property of 2-((2,6-dibenzhydryl-4-methylphenylimino)methyl)-6-tert-butyl-4-methylphenol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-((2,6-dibenzhydryl-4-methylphenylimino)methyl)-6-tert-butyl-4-methylphenol

There total 1 articles about 2-((2,6-dibenzhydryl-4-methylphenylimino)methyl)-6-tert-butyl-4-methylphenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.2%

3-tert-butyl-5-methylsalicylaldehyde (41715-31-5) + 2,6-diphenylmethyl-4-methylaniline (56138-96-6) → 2-((2,6-dibenzhydryl-4-methylphenylimino)methyl)-6-tert-butyl-4-methylphenol (1392281-16-1)

Guidance literature:

With toluene-4-sulfonic acid; In ethanol; for 12h; Reflux;

DOI:10.1016/j.jorganchem.2012.05.048

Reference yield: 64.1%

tetrachlorobis(tetrahydrofuran)titanium(IV) (31011-57-1,112925-19-6,112925-18-5) + 2-((2,6-dibenzhydryl-4-methylphenylimino)methyl)-6-tert-butyl-4-methylphenol (1392281-16-1) → trichlorotitanium 2-((2,6-dibenzhydryl-4-methylphenylimino)methyl)-6-tert-butyl-4-methylphenoxylate tetrahydrofurane monosolvate (1392281-09-2)

Guidance literature:

With KH; In toluene; N2, glove-box or Schlenk technique; to stirred soln. of iminophenol KH added at -78 °C, mixt. stirred for 3 h, TiCl4(THF)2 added at -78 °C, mixt. warmed to room temp., stirred for 24 h; solvent removed (vac.), extd. (CH2Cl2), filtrate concd. (vac.), recrystd. at -20 °C; elem. anal.;

DOI:10.1016/j.jorganchem.2012.05.048

upstream raw materials:

3-tert-butyl-5-methylsalicylaldehyde

2,6-diphenylmethyl-4-methylaniline

Downstream raw materials:

trichlorotitanium 2-((2,6-dibenzhydryl-4-methylphenylimino)methyl)-6-tert-butyl-4-methylphenoxylate tetrahydrofurane monosolvate