tris{4-[(4-{S-(trifluoromethyl)-N-[(trifluoromethyl)sulfonyl]sulfonimidoyl}phenyl)ethynyl]phenyl}amine

Base Information

Chemical Name:tris{4-[(4-{S-(trifluoromethyl)-N-[(trifluoromethyl)sulfonyl]sulfonimidoyl}phenyl)ethynyl]phenyl}amine
CAS No.:1421132-95-7
Molecular Formula:C₄₈H₂₄F₁₈N₄O₉S₆
Molecular Weight:1335.11
Hs Code.:

Synonyms:tris{4-[(4-{S-(trifluoromethyl)-N-[(trifluoromethyl)sulfonyl]sulfonimidoyl}phenyl)ethynyl]phenyl}amine

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Chemical Property of tris{4-[(4-{S-(trifluoromethyl)-N-[(trifluoromethyl)sulfonyl]sulfonimidoyl}phenyl)ethynyl]phenyl}amine

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Technology Process of tris{4-[(4-{S-(trifluoromethyl)-N-[(trifluoromethyl)sulfonyl]sulfonimidoyl}phenyl)ethynyl]phenyl}amine

There total 4 articles about tris{4-[(4-{S-(trifluoromethyl)-N-[(trifluoromethyl)sulfonyl]sulfonimidoyl}phenyl)ethynyl]phenyl}amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 1421132-99-1
S-(p-bromophenyl)-S-(trifluoromethyl)-N-[(trifluoromethyl)sulfonyl]sulfoximine

: 189178-09-4
tri(4-ethynylphenyl)amine

: 1421132-95-7
tris{4-[(4-{S-(trifluoromethyl)-N-[(trifluoromethyl)sulfonyl]sulfonimidoyl}phenyl)ethynyl]phenyl}amine

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; copper(l) iodide; triethylamine; triphenylphosphine; In toluene; at 40 ℃; for 5h; Inert atmosphere;
DOI:10.1002/chem.201103460

Reference yield:

: 4589-43-9
1-bromo-4-[(trifluoromethane)sulfinyl]benzene

: 1421132-95-7
tris{4-[(4-{S-(trifluoromethyl)-N-[(trifluoromethyl)sulfonyl]sulfonimidoyl}phenyl)ethynyl]phenyl}amine

Guidance literature:: Multi-step reaction with 4 steps

1.1: sodium hydroxide; trifluoromethylsulfonic anhydride / 16 h / -15 °C / Inert atmosphere

2.1: sodium hydroxide; potassium permanganate / water / 2 h / Inert atmosphere

3.1: sodium hydride / diethyl ether; mineral oil / 2 h / 20 °C / Inert atmosphere

3.2: 15 h / -10 - 40 °C / Inert atmosphere

4.1: copper(l) iodide; triethylamine; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenylphosphine / toluene / 5 h / 40 °C / Inert atmosphere

With potassium permanganate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; copper(l) iodide; trifluoromethylsulfonic anhydride; sodium hydride; triethylamine; triphenylphosphine; sodium hydroxide; In diethyl ether; water; toluene; mineral oil;
DOI:10.1002/chem.201103460

Reference yield:

: 1178899-26-7
N-acetyl-S-(p-bromophenyl)-S-(trifluoromethyl)sulfilimine

: 1421132-95-7
tris{4-[(4-{S-(trifluoromethyl)-N-[(trifluoromethyl)sulfonyl]sulfonimidoyl}phenyl)ethynyl]phenyl}amine

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium hydroxide; potassium permanganate / water / 2 h / Inert atmosphere

2.1: sodium hydride / diethyl ether; mineral oil / 2 h / 20 °C / Inert atmosphere

2.2: 15 h / -10 - 40 °C / Inert atmosphere

3.1: copper(l) iodide; triethylamine; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenylphosphine / toluene / 5 h / 40 °C / Inert atmosphere

With potassium permanganate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; copper(l) iodide; sodium hydride; triethylamine; triphenylphosphine; sodium hydroxide; In diethyl ether; water; toluene; mineral oil;
DOI:10.1002/chem.201103460