methyl (2R)-3-(tert-butyldiphenylsilyloxy)-2-[2,3,4,6-tetra-O-acetyl-β-D-mannopyranosyl-(1->2)-6-O-(tert-butyldiphenylsilyl)-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-glucopyranosyloxy]propanoate

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Chemical Name:methyl (2R)-3-(tert-butyldiphenylsilyloxy)-2-[2,3,4,6-tetra-O-acetyl-β-D-mannopyranosyl-(1->2)-6-O-(tert-butyldiphenylsilyl)-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-glucopyranosyloxy]propanoate
CAS No.:1353015-62-9
Molecular Formula:C₆₂H₈₂O₂₀Si₂
Molecular Weight:1203.49
Hs Code.:

methyl (2R)-3-(tert-butyldiphenylsilyloxy)-2-[2,3,4,6-tetra-O-acetyl-β-D-mannopyranosyl-(1->2)-6-O-(tert-butyldiphenylsilyl)-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-glucopyranosyloxy]propanoate

Synonyms:methyl (2R)-3-(tert-butyldiphenylsilyloxy)-2-[2,3,4,6-tetra-O-acetyl-β-D-mannopyranosyl-(1->2)-6-O-(tert-butyldiphenylsilyl)-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-glucopyranosyloxy]propanoate

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Chemical Property of methyl (2R)-3-(tert-butyldiphenylsilyloxy)-2-[2,3,4,6-tetra-O-acetyl-β-D-mannopyranosyl-(1->2)-6-O-(tert-butyldiphenylsilyl)-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-glucopyranosyloxy]propanoate

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Technology Process of methyl (2R)-3-(tert-butyldiphenylsilyloxy)-2-[2,3,4,6-tetra-O-acetyl-β-D-mannopyranosyl-(1->2)-6-O-(tert-butyldiphenylsilyl)-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-glucopyranosyloxy]propanoate

There total 4 articles about methyl (2R)-3-(tert-butyldiphenylsilyloxy)-2-[2,3,4,6-tetra-O-acetyl-β-D-mannopyranosyl-(1->2)-6-O-(tert-butyldiphenylsilyl)-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-glucopyranosyloxy]propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 1353015-61-8
phenyl 2,3,4,6-tetra-O-acetyl-β-D-mannopyranosyl-(1->2)-6-O-(tert-butyldiphenylsilyl)-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-1-thio-β-D-glucopyranoside

: 142564-20-3
(-)-methyl-(2R)-3-(tert-butyldiphenylsilyloxy)-2-hyrdoxypropanoate

: 1353015-62-9
methyl (2R)-3-(tert-butyldiphenylsilyloxy)-2-[2,3,4,6-tetra-O-acetyl-β-D-mannopyranosyl-(1->2)-6-O-(tert-butyldiphenylsilyl)-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-glucopyranosyloxy]propanoate

Guidance literature:: With N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at 0 ℃; Inert atmosphere; Molecular sieve;
DOI:10.1002/ejoc.201100934

Reference yield:

: 795305-86-1
phenyl 3,4-O-[(2S,3S)-2,3-dimethoxybutan-2,3-yl]-1-thio-β-D-glucopyranoside

: 1353015-62-9
methyl (2R)-3-(tert-butyldiphenylsilyloxy)-2-[2,3,4,6-tetra-O-acetyl-β-D-mannopyranosyl-(1->2)-6-O-(tert-butyldiphenylsilyl)-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-glucopyranosyloxy]propanoate

Guidance literature:: Multi-step reaction with 3 steps

1: 1H-imidazole / N,N-dimethyl-formamide / 12 h / 20 °C / Inert atmosphere

2: trimethylsilyl trifluoromethanesulfonate / dichloromethane / -20 °C / Inert atmosphere

3: N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate / dichloromethane / 0 °C / Inert atmosphere; Molecular sieve

With 1H-imidazole; N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/ejoc.201100934

Reference yield:

: 1353015-60-7
phenyl 6-O-(tert-butyldiphenylsilyl)-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-1-thio-β-D-glucopyranoside

: 1353015-62-9
methyl (2R)-3-(tert-butyldiphenylsilyloxy)-2-[2,3,4,6-tetra-O-acetyl-β-D-mannopyranosyl-(1->2)-6-O-(tert-butyldiphenylsilyl)-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-glucopyranosyloxy]propanoate

Guidance literature:: Multi-step reaction with 2 steps

1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / -20 °C / Inert atmosphere

2: N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate / dichloromethane / 0 °C / Inert atmosphere; Molecular sieve

With N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; In dichloromethane;
DOI:10.1002/ejoc.201100934