(4S,5S)-4,5-Bis-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropyl]-2,2-dimethyl-[1,3]dioxolane

Base Information

Chemical Name:(4S,5S)-4,5-Bis-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropyl]-2,2-dimethyl-[1,3]dioxolane
CAS No.:183745-93-9
Molecular Formula:C₄₅H₅₈O₄Si₂
Molecular Weight:719.124
Hs Code.:

Synonyms:(4S,5S)-4,5-Bis-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropyl]-2,2-dimethyl-[1,3]dioxolane

Suppliers and Price of (4S,5S)-4,5-Bis-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropyl]-2,2-dimethyl-[1,3]dioxolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of (4S,5S)-4,5-Bis-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropyl]-2,2-dimethyl-[1,3]dioxolane

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (4S,5S)-4,5-Bis-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropyl]-2,2-dimethyl-[1,3]dioxolane

There total 1 articles about (4S,5S)-4,5-Bis-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropyl]-2,2-dimethyl-[1,3]dioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 75-11-6
diiodomethane

: 183745-91-7
(4S,5S)-4,5-Bis-[(Z)-3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-2,2-dimethyl-[1,3]dioxolane

: 183745-93-9
(4S,5S)-4,5-Bis-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropyl]-2,2-dimethyl-[1,3]dioxolane

Guidance literature:: With diethylzinc; In hexane; dichloromethane; at -25 - 0 ℃; for 8h;
DOI:10.1016/0040-4020(96)00792-2

Reference yield:

: 183745-93-9
(4S,5S)-4,5-Bis-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropyl]-2,2-dimethyl-[1,3]dioxolane

: 183745-99-5
(1S,2S)-1,2-Bis-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropyl]-ethane-1,2-diol

Guidance literature:: With silica gel; iron(III) chloride; In chloroform; at 20 ℃; for 3h; Yield given;
DOI:10.1016/0040-4020(96)00792-2

Reference yield:

: 183745-93-9
(4S,5S)-4,5-Bis-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxymethyl)-cyclopropyl]-2,2-dimethyl-[1,3]dioxolane

: 133494-58-3
(1S,2R)-1-<methyl>-2-(hydroxymethyl)cyclopropane

Guidance literature:: Multi-step reaction with 3 steps

1: FeCl₃-SiO₂ / CHCl₃ / 3 h / 20 °C

2: NaIO₄ / tetrahydrofuran; H₂O / 1 h / 20 °C

3: NaBH₄ / methanol / 0.5 h / 0 °C

With sodium tetrahydroborate; sodium periodate; silica gel; iron(III) chloride; In tetrahydrofuran; methanol; chloroform; water;
DOI:10.1016/0040-4020(96)00792-2