Phosphoric acid benzyl ester (R)-2-methoxy-3-octadecyloxy-propyl ester (1R,2R,3S,6R)-2,3,6-tris-benzyloxy-cyclohexyl ester

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Chemical Name:Phosphoric acid benzyl ester (R)-2-methoxy-3-octadecyloxy-propyl ester (1R,2R,3S,6R)-2,3,6-tris-benzyloxy-cyclohexyl ester
CAS No.:310872-40-3
Molecular Formula:C₅₆H₈₁O₉P
Molecular Weight:929.227
Hs Code.:

Synonyms:Phosphoric acid benzyl ester (R)-2-methoxy-3-octadecyloxy-propyl ester (1R,2R,3S,6R)-2,3,6-tris-benzyloxy-cyclohexyl ester

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Chemical Property of Phosphoric acid benzyl ester (R)-2-methoxy-3-octadecyloxy-propyl ester (1R,2R,3S,6R)-2,3,6-tris-benzyloxy-cyclohexyl ester

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Technology Process of Phosphoric acid benzyl ester (R)-2-methoxy-3-octadecyloxy-propyl ester (1R,2R,3S,6R)-2,3,6-tris-benzyloxy-cyclohexyl ester

There total 11 articles about Phosphoric acid benzyl ester (R)-2-methoxy-3-octadecyloxy-propyl ester (1R,2R,3S,6R)-2,3,6-tris-benzyloxy-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: Phosphorous acid benzyl ester (R)-2-methoxy-3-octadecyloxy-propyl ester (1R,2R,3S,6R)-2,3,6-tris-benzyloxy-cyclohexyl ester

: 310872-40-3
Phosphoric acid benzyl ester (R)-2-methoxy-3-octadecyloxy-propyl ester (1R,2R,3S,6R)-2,3,6-tris-benzyloxy-cyclohexyl ester

Guidance literature:: With tert.-butylhydroperoxide; In dichloromethane; at 20 ℃;
DOI:10.1016/S0040-4039(00)01186-2

Reference yield:

: 17278-12-5
D-1,3,4/2,5-cyclohexanepentol

: 310872-40-3
Phosphoric acid benzyl ester (R)-2-methoxy-3-octadecyloxy-propyl ester (1R,2R,3S,6R)-2,3,6-tris-benzyloxy-cyclohexyl ester

Guidance literature:: Multi-step reaction with 10 steps

1.1: CSA / dimethylformamide / 0 - 60 °C

2.1: CS₂; DBU / dimethylformamide / 20 °C

2.2: n-Bu₃SnH; AIBN / toluene / Heating

3.1: p-TsOH / CH₂Cl₂; methanol / 0.33 h / 0 °C

4.1: NaH / dimethylformamide / 20 °C

5.1: conc. HCl / methanol / 20 °C

6.1: toluene / Heating

6.2: 86 percent / CsF / dimethylformamide / -50 - 20 °C

7.1: NaH / dimethylformamide

8.1: DABCO; RhCl(PPh₃)3 / ethanol / Heating

8.2: aq. HCl / acetone / Heating

9.1: diisopropylammonium tetrazolide / CH₂Cl₂ / Heating

9.2: tetrazole / CH₂Cl₂ / 20 °C

10.1: t-BuOOH / CH₂Cl₂ / 20 °C

With 1,4-diaza-bicyclo[2.2.2]octane; hydrogenchloride; tert.-butylhydroperoxide; carbon disulfide; RhCl(PPh₃)3; camphor-10-sulfonic acid; N,N-diisopropylamine tetrazolide; sodium hydride; toluene-4-sulfonic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; In methanol; ethanol; dichloromethane; N,N-dimethyl-formamide; toluene; 1.1: Etherification / 2.1: thiomethylation / 2.2: Barton deoxygenation / 3.1: saponification / 4.1: Alkylation / 5.1: saponification / 6.1: stannylation / 6.2: Alkylation / 7.1: Alkylation / 8.1: Isomerization / 8.2: Hydrolysis / 9.1: Substitution / 9.2: Alkylation / 10.1: Oxidation;
DOI:10.1016/S0040-4039(00)01186-2

Reference yield:

: 17230-47-6
(-)-Proto-quercitol-pentabenzoat

: 310872-40-3
Phosphoric acid benzyl ester (R)-2-methoxy-3-octadecyloxy-propyl ester (1R,2R,3S,6R)-2,3,6-tris-benzyloxy-cyclohexyl ester

Guidance literature:: Multi-step reaction with 11 steps

1.1: potassium carbinate / methanol / 20 °C

2.1: CSA / dimethylformamide / 0 - 60 °C

3.1: CS₂; DBU / dimethylformamide / 20 °C

3.2: n-Bu₃SnH; AIBN / toluene / Heating

4.1: p-TsOH / CH₂Cl₂; methanol / 0.33 h / 0 °C

5.1: NaH / dimethylformamide / 20 °C

6.1: conc. HCl / methanol / 20 °C

7.1: toluene / Heating

7.2: 86 percent / CsF / dimethylformamide / -50 - 20 °C

8.1: NaH / dimethylformamide

9.1: DABCO; RhCl(PPh₃)3 / ethanol / Heating

9.2: aq. HCl / acetone / Heating

10.1: diisopropylammonium tetrazolide / CH₂Cl₂ / Heating

10.2: tetrazole / CH₂Cl₂ / 20 °C

11.1: t-BuOOH / CH₂Cl₂ / 20 °C

With 1,4-diaza-bicyclo[2.2.2]octane; hydrogenchloride; tert.-butylhydroperoxide; carbon disulfide; RhCl(PPh₃)3; camphor-10-sulfonic acid; N,N-diisopropylamine tetrazolide; potassium formate; sodium hydride; toluene-4-sulfonic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; In methanol; ethanol; dichloromethane; N,N-dimethyl-formamide; toluene; 1.1: saponification / 2.1: Etherification / 3.1: thiomethylation / 3.2: Barton deoxygenation / 4.1: saponification / 5.1: Alkylation / 6.1: saponification / 7.1: stannylation / 7.2: Alkylation / 8.1: Alkylation / 9.1: Isomerization / 9.2: Hydrolysis / 10.1: Substitution / 10.2: Alkylation / 11.1: Oxidation;
DOI:10.1016/S0040-4039(00)01186-2