Acetic acid (3aS,4S,6R,7R,7aS)-6-acetoxymethyl-4-(4-nitro-phenoxy)-2-oxo-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester

Base Information

• Chemical Name: Acetic acid (3aS,4S,6R,7R,7aS)-6-acetoxymethyl-4-(4-nitro-phenoxy)-2-oxo-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester
• CAS No.: 60869-86-5
• Molecular Formula: C₁₇H₁₇NO₁₁
• Molecular Weight: 411.322
• Mol file: 60869-86-5.mol

Synonyms:Acetic acid (3aS,4S,6R,7R,7aS)-6-acetoxymethyl-4-(4-nitro-phenoxy)-2-oxo-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester

Chemical Property of Acetic acid (3aS,4S,6R,7R,7aS)-6-acetoxymethyl-4-(4-nitro-phenoxy)-2-oxo-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Acetic acid (3aS,4S,6R,7R,7aS)-6-acetoxymethyl-4-(4-nitro-phenoxy)-2-oxo-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester

There total 2 articles about Acetic acid (3aS,4S,6R,7R,7aS)-6-acetoxymethyl-4-(4-nitro-phenoxy)-2-oxo-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

4,6-di-O-acetyl-2,3-O-carbonyl-α-D-mannopyranosyl bromide (53958-21-7) + potassium 4-nitrophenolate (1124-31-8) → Acetic acid (3aS,4S,6R,7R,7aS)-6-acetoxymethyl-4-(4-nitro-phenoxy)-2-oxo-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester (60869-86-5)

Guidance literature:

perhydrodibenzo-18-crown-6; In acetonitrile; Ambient temperature;

DOI:10.1016/0008-6215(88)84013-8

Reference yield:

→ Acetic acid (3aS,4S,6R,7R,7aS)-6-acetoxymethyl-4-(4-nitro-phenoxy)-2-oxo-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester (60869-86-5)

Guidance literature:

aus Bromid 1, Salz 3;

DOI:10.1016/S0008-6215(00)83227-9

Reference yield: 47.0%

Acetic acid (3aS,4S,6R,7R,7aS)-6-acetoxymethyl-4-(4-nitro-phenoxy)-2-oxo-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl ester (60869-86-5) → 4-nitrophenyl-β-D-mannopyranoside (35599-02-1)

Guidance literature:

With Dowex-1 (basic) resin; In methanol; Ambient temperature;

DOI:10.1016/0008-6215(88)84013-8

upstream raw materials:

4,6-di-O-acetyl-2,3-O-carbonyl-α-D-mannopyranosyl bromide

potassium 4-nitrophenolate

Downstream raw materials:

4-nitrophenyl-β-D-mannopyranoside