Phenol, 4-nitro-,potassium salt (1:1)

Base Information

• Chemical Name: Phenol, 4-nitro-,potassium salt (1:1)
• CAS No.: 1124-31-8
• Molecular Formula: C6H5 N O3 . K
• Molecular Weight: 177.201
• Mol file: 1124-31-8.mol

Synonyms:Phenol,4-nitro-, potassium salt (9CI); Phenol, p-nitro-, potassium deriv. (6CI);Phenol, p-nitro-, potassium salt (8CI); Potassium, (p-nitrophenoxy)- (7CI);4-Nitrophenol potassium salt; Potassium 4-nitrophenolate; Potassium4-nitrophenoxide; Potassium p-nitrophenate; Potassium p-nitrophenolate;Potassium p-nitrophenoxide; p-Nitrophenol potassium salt

Chemical Property of Phenol, 4-nitro-,potassium salt (1:1)

Chemical Property:

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s): 3
• Hazard Codes: 3:
• Safety Statements: It may explode spontaneously in storage. When heated to decomposition it e"> x and K2O. See also NITRO COMPOUNDS." target="_blank">It may explode spontaneously in storage. When heated to decomposition it e

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phenol, 4-nitro-,potassium salt (1:1)

There total 41 articles about Phenol, 4-nitro-,potassium salt (1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) → potassium 4-nitrophenolate (1124-31-8)

Guidance literature:

With potassium hydroxide; In water; for 0.25h;

DOI:10.1021/acs.joc.9b01485

Reference yield: 80.0%

para-methoxynitrobenzene (100-17-4) → potassium 4-nitrophenolate (1124-31-8)

Guidance literature:

With Triton X-114; potassium thioacyanate; at 180 ℃; for 3h; Activation energy;

DOI:10.1016/j.tetlet.2005.11.048

Reference yield:

2C6H5NO3*C6H4NO3(1-)*K(1+) → 4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + potassium 4-nitrophenolate (1124-31-8)

Guidance literature:

In acetonitrile; Equilibrium constant;

DOI:10.1021/jo00133a001

upstream raw materials:

4-nitro-phenol

potassium acetate

4-(4-nitro-phenoxy)-azetidin-2-one

p-nitrophenyl acetate-d3

Downstream raw materials:

2-(3-nitrophenoxy)pyridine

1-(4-bromobutoxy)-4-nitrobenzene

1-nitro-4-(4-(4-nitrophenoxy)butoxy)benzene

furan-2-carboxylic acid-(2-nitro-phenyl ester)

Refernces

• 1、 Kovach, Ildiko M.. "TRANSITION STATES OF SOME ACYL TRANSFER REACTIONS IN ACETONITRILE". . p. 4309 - 4312. Retrieved 1980.
• 2、 Buncel, Erwin,Nagelkerke, Ruby,Thatcher, Gregory R.J.. "Alkali metal ion catalysis in nucleophilic displacement by ethoxide ion on p-nitrophenyl phenylphosphonate: Evidence for multiple metal ion catalysis1". . p. 53 - 63. Retrieved 2003.
• 3、 Legault, Claude Y.,Mayer, Robert J.,Mayr, Herbert,Ofial, Armin R.. "Lewis Acidity Scale of Diaryliodonium Ions toward Oxygen, Nitrogen, and Halogen Lewis Bases". supporting information. . Retrieved 2020/03/13.
• 4、 Chile,Ebrahimi,Wong,Aluthge,Hatzikiriakos,Mehrkhodavandi. "Impact of aryloxy initiators on the living and immortal polymerization of lactide". . p. 6723 - 6733. Retrieved 2017/07/10.