1,2-Epoxy-5-hexene

Base Information

• Chemical Name: 1,2-Epoxy-5-hexene
• CAS No.: 10353-53-4
• Molecular Formula: C6H10O
• Molecular Weight: 98.1448
• Hs Code.: 29109000
• European Community (EC) Number: 233-771-9
• DSSTox Substance ID: DTXSID20908458
• Nikkaji Number: J236.281C
• Mol file: 10353-53-4.mol

Synonyms:1,2-epoxy-5-hexene

Chemical Property of 1,2-Epoxy-5-hexene

Chemical Property:

• Appearance/Colour: clear colorless liquid
• Vapor Pressure: 18.6mmHg at 25°C
• Refractive Index: 1.424-1.426
• Boiling Point: 119.999 °C at 760 mmHg
• Flash Point: 15.556 °C
• PSA: 12.53000
• Density: 0.892 g/cm³
• LogP: 1.35140
• Storage Temp.: Refrigerator (+4°C) + Flammables area
• Solubility.: soluble in Methanol
• XLogP3: 1.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 98.073164938
• Heavy Atom Count: 7
• Complexity: 68.6

Purity/Quality:

98% ^*data from raw suppliers

1,2-Epoxy-5-hexene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T, F
• Hazard Codes: T-F,T,F
• Statements: 45-36/37/38-20/21/22-11-48/20/21/22-41-37/38-46-25
• Safety Statements: 53-45-37/39-26-16-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCCC1CO1

Technology Process of 1,2-Epoxy-5-hexene

There total 6 articles about 1,2-Epoxy-5-hexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

1-Chloro-5-hexen-2-ol (10293-98-8) → 1,2-epoxy-5-hexene (10353-53-4)

Guidance literature:

With sodium hydroxide; In ethylene glycol; for 1h; Ambient temperature;

DOI:10.1021/jo00303a018

Reference yield: 65.0%

1,5-Hexadien (592-42-7) → 1,2-epoxy-5-hexene (10353-53-4)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In chloroform; Ambient temperature;

Reference yield:

1,5-Hexadien (592-42-7) → 1,2-epoxy-5-hexene (10353-53-4) + hexa-2,4-diene (592-46-1) + 1,5-hexadiene diepoxide (1888-89-7,74892-51-6,74892-53-8,131722-62-8)

Guidance literature:

With dihydrogen peroxide; In methanol; water; at 64.84 ℃; for 2h; regioselective reaction;

DOI:10.1016/j.molcata.2010.05.024

upstream raw materials:

Perbenzoic acid

1,5-Hexadien

1-Chloro-5-hexen-2-ol

Downstream raw materials:

(E)-6-phenylhex-2-en-1-ol

(Z)-6-phenyl-2-hexen-1-ol

C₁₃H₁₇NO₂

(E)-(5R,7S)-7-Benzenesulfonyl-deca-1,8-dien-5-ol