C₄₈H₅₂ClNO₁₃S

Base Information

• Chemical Name: C₄₈H₅₂ClNO₁₃S
• CAS No.: 949000-05-9
• Molecular Formula: C₄₈H₅₂ClNO₁₃S
• Molecular Weight: 918.459
• Mol file: 949000-05-9.mol

Synonyms:C₄₈H₅₂ClNO₁₃S

Chemical Property of C₄₈H₅₂ClNO₁₃S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄₈H₅₂ClNO₁₃S

There total 3 articles about C₄₈H₅₂ClNO₁₃S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

N-benzyl-2-amino-6-O-benzyl-2,3-N,O-carbonyl-4-O-chloroacetyl-2-deoxy-α-D-glucopyranosyl bromide (910805-67-3) + C25H30O7S (948999-99-3) → C48H52ClNO13S (949000-05-9)

Guidance literature:

With 2,6-di-tert-butyl-4-methylpyridine; 4 A molecular sieve; silver trifluoromethanesulfonate; In 1,4-dioxane; toluene; at 0 - 20 ℃;

DOI:10.1021/jo070669p

Reference yield:

2,6-dimethylphenyl 4,6-O-benzylidene-1-thio-β-galactopyranoside → C48H52ClNO13S (949000-05-9)

Guidance literature:

Multi-step reaction with 3 steps

1: 90 percent / pyridine / 20 °C

2: 84 percent / HCl; NaBH₃CN; molecular sieves 3 Angstroem / dioxane; tetrahydrofuran / 0.5 h / 0 °C

3: 93 percent / 2,6-di-tert-butyl-4-methylpyridine; AgOTf; molecular sieves 4 Angstroem / dioxane; toluene / 0 - 20 °C

With pyridine; hydrogenchloride; 2,6-di-tert-butyl-4-methylpyridine; 3 A molecular sieve; 4 A molecular sieve; silver trifluoromethanesulfonate; sodium cyanoborohydride; In tetrahydrofuran; 1,4-dioxane; toluene;

DOI:10.1021/jo070669p

Reference yield:

C25H28O7S → C48H52ClNO13S (949000-05-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 84 percent / HCl; NaBH₃CN; molecular sieves 3 Angstroem / dioxane; tetrahydrofuran / 0.5 h / 0 °C

2: 93 percent / 2,6-di-tert-butyl-4-methylpyridine; AgOTf; molecular sieves 4 Angstroem / dioxane; toluene / 0 - 20 °C

With hydrogenchloride; 2,6-di-tert-butyl-4-methylpyridine; 3 A molecular sieve; 4 A molecular sieve; silver trifluoromethanesulfonate; sodium cyanoborohydride; In tetrahydrofuran; 1,4-dioxane; toluene;

DOI:10.1021/jo070669p

upstream raw materials:

N-benzyl-2-amino-6-O-benzyl-2,3-N,O-carbonyl-4-O-chloroacetyl-2-deoxy-α-D-glucopyranosyl bromide

C₂₅H₃₀O₇S

Downstream raw materials:

C₇₅H₇₅ClN₂O₂₁

C₆₈H₆₉ClN₂O₂₀

C₇₀H₆₉Cl₄N₃O₂₀

C₅₄H₆₁ClN₄O₁₈