HOC₆H₂(C(CH₃)3)2CHNCH₂C₇H₄N₂CH₃

Base Information

• Chemical Name: HOC₆H₂(C(CH₃)3)2CHNCH₂C₇H₄N₂CH₃
• CAS No.: 1144550-16-2
• Molecular Formula: C₂₄H₃₁N₃O
• Molecular Weight: 377.53
• Mol file: 1144550-16-2.mol

Synonyms:HOC₆H₂(C(CH₃)3)2CHNCH₂C₇H₄N₂CH₃

Chemical Property of HOC₆H₂(C(CH₃)3)2CHNCH₂C₇H₄N₂CH₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of HOC₆H₂(C(CH₃)3)2CHNCH₂C₇H₄N₂CH₃

There total 1 articles about HOC₆H₂(C(CH₃)3)2CHNCH₂C₇H₄N₂CH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

3,5-di-tert-butyl-2-hydroxybenzaldehyde (37942-07-7) + 2-aminomethyl-1-methylbenzimidazole dihydrochloride (53332-79-9) → HOC6H2(C(CH3)3)2CHNCH2C7H4N2CH3 (1144550-16-2)

Guidance literature:

With potassium carbonate; In methanol; water; at 20 ℃; for 12h;

DOI:10.1016/j.jorganchem.2008.11.064

Reference yield: 90.0%

HOC6H2(C(CH3)3)2CHNCH2C7H4N2CH3 (1144550-16-2) + tetra(benzyl)hafnium (31406-67-4) → [Hf(OC6H2(C(CH3)3)2CH(CH2C6H5)NCH2C7H4N2CH3)(CH2C6H5)2] (1144550-35-5)

Guidance literature:

In toluene; (N2); using Schlenk techniques; addn. of soln. of HOC6H2(t-Bu)2CHNCH2C7H4N2Me in toluene to soln. of Hf(CH2Ph)4 in toluene; stirring at 50°C for 24 h; removal of volatiles under reduced pressure; washing with cold pentane; filtration, drying under vac., elem. anal.;

DOI:10.1016/j.jorganchem.2008.11.064

Reference yield: 86.0%

HOC6H2(C(CH3)3)2CHNCH2C7H4N2CH3 (1144550-16-2) + tetrabenzylzirconium(IV) (24356-01-2) → [Zr(OC6H2(C(CH3)3)2CH(CH2C6H5)NCH2C7H4N2CH3)(CH2C6H5)2] (1144550-33-3)

Guidance literature:

In toluene; (N2); using Schlenk techniques; addn. of soln. of HOC6H2(t-Bu)2CHNCH2C7H4N2Me in toluene to soln. of Zr(CH2Ph)4 in toluene; stirring at 40°C overnight; removal of volatiles under reduced pressure; washing with cold pentane; filtration, drying under vac., elem. anal.;

DOI:10.1016/j.jorganchem.2008.11.064

upstream raw materials:

3,5-di-tert-butyl-2-hydroxybenzaldehyde

2-aminomethyl-1-methylbenzimidazole dihydrochloride

Downstream raw materials:

[Zr(OC₆H₂(C(CH₃)3)2CH(CH₂C₆H₅)NCH₂C₇H₄N₂CH₃)(CH₂C₆H₅)2]

[Hf(OC₆H₂(C(CH₃)3)2CH(CH₂C₆H₅)NCH₂C₇H₄N₂CH₃)(CH₂C₆H₅)2]

[Hf(CH₂C₆H₅)3(OC₆H₂(C(CH₃)3)2CHNCH₂C₇H₄N₂CH₃)]

Refernces