(2R,5Z,8S,9R)-8-benzyloxy-9-(tert-butyldiphenylsilanyloxymethyl)-2-methoxy-2,3,4,7,8,9-hexahydrooxonine-2-carbaldehyde

Base Information

Chemical Name:(2R,5Z,8S,9R)-8-benzyloxy-9-(tert-butyldiphenylsilanyloxymethyl)-2-methoxy-2,3,4,7,8,9-hexahydrooxonine-2-carbaldehyde
CAS No.:1172121-47-9
Molecular Formula:C₃₄H₄₂O₅Si
Molecular Weight:558.79
Hs Code.:

Synonyms:(2R,5Z,8S,9R)-8-benzyloxy-9-(tert-butyldiphenylsilanyloxymethyl)-2-methoxy-2,3,4,7,8,9-hexahydrooxonine-2-carbaldehyde

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Chemical Property of (2R,5Z,8S,9R)-8-benzyloxy-9-(tert-butyldiphenylsilanyloxymethyl)-2-methoxy-2,3,4,7,8,9-hexahydrooxonine-2-carbaldehyde

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Technology Process of (2R,5Z,8S,9R)-8-benzyloxy-9-(tert-butyldiphenylsilanyloxymethyl)-2-methoxy-2,3,4,7,8,9-hexahydrooxonine-2-carbaldehyde

There total 1 articles about (2R,5Z,8S,9R)-8-benzyloxy-9-(tert-butyldiphenylsilanyloxymethyl)-2-methoxy-2,3,4,7,8,9-hexahydrooxonine-2-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1172121-46-8
C₄₂H₅₀O₆SeSi

: 1172121-47-9
(2R,5Z,8S,9R)-8-benzyloxy-9-(tert-butyldiphenylsilanyloxymethyl)-2-methoxy-2,3,4,7,8,9-hexahydrooxonine-2-carbaldehyde

Guidance literature:: With potassium carbonate; In methanol; dichloromethane; at 20 ℃; for 18h; Inert atmosphere;
DOI:10.1016/j.tetasy.2009.03.010

Reference yield: 100.0%

: 1172121-47-9
(2R,5Z,8S,9R)-8-benzyloxy-9-(tert-butyldiphenylsilanyloxymethyl)-2-methoxy-2,3,4,7,8,9-hexahydrooxonine-2-carbaldehyde

: 1172121-53-7
(2R,8S,9R)-8-benzyloxy-9-(tert-butyldiphenylsilanyloxymethyl)-2-methoxy-2,3,4,5,6,7,8,9-octahydrooxonine-2-carbaldehyde

Guidance literature:: With platinum(IV) oxide; hydrogen; In ethyl acetate; for 3.5h;
DOI:10.1016/j.tetasy.2009.03.010

Reference yield: 85.0%

: 1172121-47-9
(2R,5Z,8S,9R)-8-benzyloxy-9-(tert-butyldiphenylsilanyloxymethyl)-2-methoxy-2,3,4,7,8,9-hexahydrooxonine-2-carbaldehyde

: 1779-49-3
Methyltriphenylphosphonium bromide

: 1172121-48-0
(2R,5Z,8S,9R)-8-benzyloxy-9-(tert-butyldiphenylsilanyloxymethyl)-2-methoxy-2-vinyl-2,3,4,7,8,9-hexahydrooxonine

Guidance literature:: Methyltriphenylphosphonium bromide; With sodium hydride; In dimethyl sulfoxide; at 20 ℃; for 0.166667h; Inert atmosphere;

(2R,5Z,8S,9R)-8-benzyloxy-9-(tert-butyldiphenylsilanyloxymethyl)-2-methoxy-2,3,4,7,8,9-hexahydrooxonine-2-carbaldehyde; In dimethyl sulfoxide; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1016/j.tetasy.2009.03.010