(η5-2,5-t-Bu2C4H2N)Sc(III)(o-dimethylaminobenzyl)[B(C6F5)4]

Base Information

• Chemical Name: (η5-2,5-t-Bu2C4H2N)Sc(III)(o-dimethylaminobenzyl)[B(C6F5)4]
• CAS No.: 1033783-35-5
• Molecular Formula: C₂₁H₃₂N₂Sc*C₂₄BF₂₀
• Molecular Weight: 1036.5
• Mol file: 1033783-35-5.mol

Synonyms:(η5-2,5-t-Bu2C4H2N)Sc(III)(o-dimethylaminobenzyl)[B(C6F5)4]

Chemical Property of (η5-2,5-t-Bu2C4H2N)Sc(III)(o-dimethylaminobenzyl)[B(C6F5)4]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η5-2,5-t-Bu2C4H2N)Sc(III)(o-dimethylaminobenzyl)[B(C6F5)4]

There total 1 articles about (η5-2,5-t-Bu2C4H2N)Sc(III)(o-dimethylaminobenzyl)[B(C6F5)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(η5-2,5-t-Bu2C4H2N)Sc(III)(bis(o-dimethylaminobenzyl)) (1033783-30-0) + trityl tetrakis(pentafluorophenyl)borate → (η5-2,5-t-Bu2C4H2N)Sc(III)(o-dimethylaminobenzyl)[B(C6F5)4] (1033783-35-5)

Guidance literature:

In toluene; toluene soln. of Sc complex added to (Ph3C)B(C6F5)4 in toluene at room temp., stirred for 5 min; solvent removed under reduced pressure; washed by hexane; dried under vac.;

DOI:10.1039/b719182k

Reference yield: 88.0%

1,2-dimethoxyethane (110-71-4) + (η5-2,5-t-Bu2C4H2N)Sc(III)(o-dimethylaminobenzyl)[B(C6F5)4] (1033783-35-5) → [(η5-2,5-t-Bu2C4H2N)Sc(III)(o-dimethylaminobenzyl)(DME)][B(C6F5)4] (1033783-37-7)

Guidance literature:

In toluene; DME added to toluene soln. of Sc complex at room temp., stirred for 5 min; solvent removed under reduced pressure; washed by hexane; dried under vac., recrystd. from hexane-toluene-DME at room temp.; detd. by XRD;

DOI:10.1039/b719182k

upstream raw materials:

(η5-2,5-t-Bu2C4H2N)Sc(III)(bis(o-dimethylaminobenzyl))

Downstream raw materials:

[(η5-2,5-t-Bu2C4H2N)Sc(III)(o-dimethylaminobenzyl)(DME)][B(C6F5)4]