(S)-(E)-4-(dimethylphenylsilyl)-2-decene

Base Information

• Chemical Name: (S)-(E)-4-(dimethylphenylsilyl)-2-decene
• CAS No.: 176198-95-1
• Molecular Formula: C₁₈H₃₀Si
• Molecular Weight: 274.522
• Mol file: 176198-95-1.mol

Synonyms:(S)-(E)-4-(dimethylphenylsilyl)-2-decene

Chemical Property of (S)-(E)-4-(dimethylphenylsilyl)-2-decene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of (S)-(E)-4-(dimethylphenylsilyl)-2-decene

There total 6 articles about (S)-(E)-4-(dimethylphenylsilyl)-2-decene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

(5S,6R)-5-[(S)-1-(Dimethyl-phenyl-silanyl)-heptyl]-6-methyl-2,2,4,4-tetraphenyl-[1,3,2,4]dioxadisilinane (189247-56-1) → (S)-(E)-4-(dimethylphenylsilyl)-2-decene (176198-95-1)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.25h;

DOI:10.1002/chem.200401031

Reference yield: 49.0%

C30H40OSi2 (175982-50-0) → (5S,6R)-5-[(S)-1-(Dimethyl-phenyl-silanyl)-heptyl]-6-methyl-2,2,4,4-tetraphenyl-[1,3,2,4]dioxadisilinane (189247-56-1) + (S)-(E)-4-(dimethylphenylsilyl)-2-decene (176198-95-1)

Guidance literature:

With 1,1,3,3-tetramethylbutane isonitrile; palladium(II) acetylacetonate; In toluene; for 3h; Heating;

DOI:10.1002/chem.200401031

Reference yield:

C30H40OSi2 (175982-51-1) → (S)-(E)-4-(dimethylphenylsilyl)-2-decene (176198-95-1) + (R)-(E)-4-(dimethylphenylsilyl)-2-decene

Guidance literature:

C₃₀H₄₀OSi₂; With 1,1,3,3-tetramethylbutane isonitrile; palladium(II) acetylacetonate; In toluene; for 1h; Heating;

With phenyllithium; In tetrahydrofuran; cyclohexane; at 0 ℃; for 0.25h; Title compound not separated from byproducts;

DOI:10.1002/chem.200401031

upstream raw materials:

(5S,6R)-5-[(S)-1-(Dimethyl-phenyl-silanyl)-heptyl]-6-methyl-2,2,4,4-tetraphenyl-[1,3,2,4]dioxadisilinane

C₃₀H₄₀OSi₂

C₃₀H₄₀OSi₂

1-chloro-2,2-dimethyl-1,1,2-triphenyl-disilane

Downstream raw materials:

C₃₀H₄₀OSi₂

(S)-decan-4-ol

Refernces