(5S,6R)-5-[(S)-1-(Dimethyl-phenyl-silanyl)-heptyl]-6-methyl-2,2,4,4-tetraphenyl-[1,3,2,4]dioxadisilinane

Base Information

• Chemical Name: (5S,6R)-5-[(S)-1-(Dimethyl-phenyl-silanyl)-heptyl]-6-methyl-2,2,4,4-tetraphenyl-[1,3,2,4]dioxadisilinane
• CAS No.: 189247-56-1
• Molecular Formula: C₄₂H₅₀O₂Si₃
• Molecular Weight: 671.114
• Mol file: 189247-56-1.mol

Synonyms:(5S,6R)-5-[(S)-1-(Dimethyl-phenyl-silanyl)-heptyl]-6-methyl-2,2,4,4-tetraphenyl-[1,3,2,4]dioxadisilinane

Chemical Property of (5S,6R)-5-[(S)-1-(Dimethyl-phenyl-silanyl)-heptyl]-6-methyl-2,2,4,4-tetraphenyl-[1,3,2,4]dioxadisilinane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (5S,6R)-5-[(S)-1-(Dimethyl-phenyl-silanyl)-heptyl]-6-methyl-2,2,4,4-tetraphenyl-[1,3,2,4]dioxadisilinane

There total 3 articles about (5S,6R)-5-[(S)-1-(Dimethyl-phenyl-silanyl)-heptyl]-6-methyl-2,2,4,4-tetraphenyl-[1,3,2,4]dioxadisilinane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

C30H40OSi2 (175982-50-0) → (5S,6R)-5-[(S)-1-(Dimethyl-phenyl-silanyl)-heptyl]-6-methyl-2,2,4,4-tetraphenyl-[1,3,2,4]dioxadisilinane (189247-56-1) + (S)-(E)-4-(dimethylphenylsilyl)-2-decene (176198-95-1)

Guidance literature:

With 1,1,3,3-tetramethylbutane isonitrile; palladium(II) acetylacetonate; In toluene; for 3h; Heating;

DOI:10.1002/chem.200401031

Reference yield:

1-chloro-2,2-dimethyl-1,1,2-triphenyl-disilane (18666-34-7) → (5S,6R)-5-[(S)-1-(Dimethyl-phenyl-silanyl)-heptyl]-6-methyl-2,2,4,4-tetraphenyl-[1,3,2,4]dioxadisilinane (189247-56-1)

Guidance literature:

Multi-step reaction with 2 steps

1: Et₃N; 4-dimethylaminopyridine / tetrahydrofuran / 20 °C

2: 46 percent / 1,1,3,3-tetramethylbutyl isocyanide / [Pd(acac)2] / toluene / 3 h / Heating

With dmap; 1,1,3,3-tetramethylbutane isonitrile; triethylamine; palladium(II) acetylacetonate; In tetrahydrofuran; toluene;

DOI:10.1002/chem.200401031

Reference yield:

(E)-(R)-Dec-3-en-2-ol → (5S,6R)-5-[(S)-1-(Dimethyl-phenyl-silanyl)-heptyl]-6-methyl-2,2,4,4-tetraphenyl-[1,3,2,4]dioxadisilinane (189247-56-1)

Guidance literature:

Multi-step reaction with 2 steps

1: Et₃N; 4-dimethylaminopyridine / tetrahydrofuran / 20 °C

2: 46 percent / 1,1,3,3-tetramethylbutyl isocyanide / [Pd(acac)2] / toluene / 3 h / Heating

With dmap; 1,1,3,3-tetramethylbutane isonitrile; triethylamine; palladium(II) acetylacetonate; In tetrahydrofuran; toluene;

DOI:10.1002/chem.200401031

upstream raw materials:

C₃₀H₄₀OSi₂

1-chloro-2,2-dimethyl-1,1,2-triphenyl-disilane

Downstream raw materials:

(S)-(E)-4-(dimethylphenylsilyl)-2-decene

C₃₀H₄₀OSi₂

(S)-decan-4-ol