2-cyano-3-[3',4-di-n-hexyl-5'-(9-phenyl-9H-carbazol-3-yl)-[2,2']bithiophen-5-yl]acrylic acid

Base Information

Chemical Name:2-cyano-3-[3',4-di-n-hexyl-5'-(9-phenyl-9H-carbazol-3-yl)-[2,2']bithiophen-5-yl]acrylic acid
CAS No.:1350827-00-7
Molecular Formula:C₄₂H₄₂N₂O₂S₂
Molecular Weight:670.94
Hs Code.:

Synonyms:2-cyano-3-[3',4-di-n-hexyl-5'-(9-phenyl-9H-carbazol-3-yl)-[2,2']bithiophen-5-yl]acrylic acid

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Chemical Property of 2-cyano-3-[3',4-di-n-hexyl-5'-(9-phenyl-9H-carbazol-3-yl)-[2,2']bithiophen-5-yl]acrylic acid

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Technology Process of 2-cyano-3-[3',4-di-n-hexyl-5'-(9-phenyl-9H-carbazol-3-yl)-[2,2']bithiophen-5-yl]acrylic acid

There total 5 articles about 2-cyano-3-[3',4-di-n-hexyl-5'-(9-phenyl-9H-carbazol-3-yl)-[2,2']bithiophen-5-yl]acrylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 1350826-99-1
C₃₉H₄₁NOS₂

: 372-09-8
cyanoacetic acid

: 1350827-00-7
2-cyano-3-[3',4-di-n-hexyl-5'-(9-phenyl-9H-carbazol-3-yl)-[2,2']bithiophen-5-yl]acrylic acid

Guidance literature:: With piperidine; In acetonitrile; at 110 ℃; for 15h;
DOI:10.5012/bkcs.2012.33.1.293

Reference yield:

: 3-[3,4’-dihexyl(2,2’-bithiophene)-5-yl]-9-phenylcarbazole

: 1350827-00-7
2-cyano-3-[3',4-di-n-hexyl-5'-(9-phenyl-9H-carbazol-3-yl)-[2,2']bithiophen-5-yl]acrylic acid

Guidance literature:: Multi-step reaction with 2 steps

1: trichlorophosphate / 5 h / 0 - 80 °C

2: piperidine / acetonitrile / 15 h / 110 °C

With piperidine; trichlorophosphate; In acetonitrile; 2: Knoevenagel condensation;
DOI:10.5012/bkcs.2012.33.1.293

Reference yield:

: C₂₀H₁₈BNO₂

: 1350827-00-7
2-cyano-3-[3',4-di-n-hexyl-5'-(9-phenyl-9H-carbazol-3-yl)-[2,2']bithiophen-5-yl]acrylic acid

Guidance literature:: Multi-step reaction with 4 steps

1: hydrogenchloride / water / 1 h

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; Aliquat 336; potassium carbonate / tetrahydrofuran / 68 h / Reflux

3: trichlorophosphate / 5 h / 0 - 80 °C

4: piperidine / acetonitrile / 15 h / 110 °C

With piperidine; hydrogenchloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; Aliquat 336; potassium carbonate; trichlorophosphate; In tetrahydrofuran; water; acetonitrile; 2: Suzuki coupling / 4: Knoevenagel condensation;
DOI:10.5012/bkcs.2012.33.1.293