4-(E-2-ethoxycarbonylvinyl)-2,3-di(trifluoromethyl)phenyl trifluoromethanesulfonate

Base Information

Chemical Name:4-(E-2-ethoxycarbonylvinyl)-2,3-di(trifluoromethyl)phenyl trifluoromethanesulfonate
CAS No.:306988-12-5
Molecular Formula:C₁₄H₉F₉O₅S
Molecular Weight:460.274
Hs Code.:

Synonyms:4-(E-2-ethoxycarbonylvinyl)-2,3-di(trifluoromethyl)phenyl trifluoromethanesulfonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4-(E-2-ethoxycarbonylvinyl)-2,3-di(trifluoromethyl)phenyl trifluoromethanesulfonate

Chemical Property:

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Technology Process of 4-(E-2-ethoxycarbonylvinyl)-2,3-di(trifluoromethyl)phenyl trifluoromethanesulfonate

There total 5 articles about 4-(E-2-ethoxycarbonylvinyl)-2,3-di(trifluoromethyl)phenyl trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 301179-91-9
4-(E-2-ethoxycarbonylvinyl)-2,3-di(trifluoromethyl)phenol

: 358-23-6
trifluoromethylsulfonic anhydride

: 306988-12-5
4-(E-2-ethoxycarbonylvinyl)-2,3-di(trifluoromethyl)phenyl trifluoromethanesulfonate

Guidance literature:: With pyridine; at 0 - 20 ℃; for 2.5h;
DOI:10.1021/ol0064359

Reference yield:

: 140-88-5,9003-32-1
ethyl acrylate

: 306988-12-5
4-(E-2-ethoxycarbonylvinyl)-2,3-di(trifluoromethyl)phenyl trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / tributylstannylfuran; tri(o-tolyl) phosphine; Et₃N / Pd₂(dba)3 / dimethylformamide / 15 h / 70 °C

2: 98 percent / pyridine / 2.5 h / 0 - 20 °C

With pyridine; 2-(tributylstannyl)furan; triethylamine; tris-(o-tolyl)phosphine; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In N,N-dimethyl-formamide; 1: Heck reaction / 2: Esterification;
DOI:10.1021/ol0064359

Reference yield:

: 306988-01-2
2,3-di(trifluoromethyl)-4-iodophenol

: 306988-12-5
4-(E-2-ethoxycarbonylvinyl)-2,3-di(trifluoromethyl)phenyl trifluoromethanesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / tributylstannylfuran; tri(o-tolyl) phosphine; Et₃N / Pd₂(dba)3 / dimethylformamide / 15 h / 70 °C

2: 98 percent / pyridine / 2.5 h / 0 - 20 °C

With pyridine; 2-(tributylstannyl)furan; triethylamine; tris-(o-tolyl)phosphine; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In N,N-dimethyl-formamide; 1: Heck reaction / 2: Esterification;
DOI:10.1021/ol0064359