4-(1H-imidazo [4,5-f][1,10]-phenanthrolin-2-yl)-2-methoxyphenol

Base Information

• Chemical Name: 4-(1H-imidazo [4,5-f][1,10]-phenanthrolin-2-yl)-2-methoxyphenol
• CAS No.: 300357-18-0
• Molecular Formula: C₂₀H₁₄N₄O₂
• Molecular Weight: 342.357
• Mol file: 300357-18-0.mol

Synonyms:4-(1H-imidazo [4,5-f][1,10]-phenanthrolin-2-yl)-2-methoxyphenol

Chemical Property of 4-(1H-imidazo [4,5-f][1,10]-phenanthrolin-2-yl)-2-methoxyphenol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-(1H-imidazo [4,5-f][1,10]-phenanthrolin-2-yl)-2-methoxyphenol

There total 1 articles about 4-(1H-imidazo [4,5-f][1,10]-phenanthrolin-2-yl)-2-methoxyphenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,10-phenanthroline-5,6-dione (27318-90-7) + vanillin (121-33-5,8014-42-4) → 4-(1H-imidazo [4,5-f][1,10]-phenanthrolin-2-yl)-2-methoxyphenol (300357-18-0)

Guidance literature:

With ammonium acetate; acetic acid; at 85 ℃; for 8h;

DOI:10.1016/j.ejphar.2019.01.047

Reference yield: 80.0%

cadmium(II) nitrate tetrhydrate + naphthalene-1,4-dicarboxylic acid (605-70-9) + 4-(1H-imidazo [4,5-f][1,10]-phenanthrolin-2-yl)-2-methoxyphenol (300357-18-0) → [Cd(4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)-2-methoxyphenol)(naphthalene-1,4-dicarboxylate)] (1332625-21-4)

Guidance literature:

In water; High Pressure; under hydrothermal conditions; mixt. of N4C13H7C6H3(OH)OCH3, Cd salt andnaphthalene-1,4-dicarboxylic acid in distd. H2O heated at 170°C for 3 d in stainless vessel; cooled to room temp. (5°C/h); crystals obtained; elem. anal.;

DOI:10.1016/j.molstruc.2011.07.025

Reference yield: 73.0%

bis(2,2'-bipyridine)dichlororuthenium(II) dihydrate + sodium perchlorate + water (7732-18-5) + 4-(1H-imidazo [4,5-f][1,10]-phenanthrolin-2-yl)-2-methoxyphenol (300357-18-0) → [Ru(2,2'-bipyridine)2(2-(3-methoxy-4-hydroxyphenyl)imidazolo[f]-1,10-phenanthroline)]

Guidance literature:

In ethanol; water; byproducts: NaCl; a mixt. of complex and phenanthroline in ethanol-water was refluxed under N2 fo 5 h, cooled, satd. aq. NaClO4 was added; ppt. was vac.-filtered, washed with cold water and diethyl ether, dried under vac., chromd. on silica gel (acetonitrile-toluene 2/1), recrystd. from acetone-toluene (1/1); elem. anal.;

DOI:10.1016/j.saa.2004.01.002

upstream raw materials:

1,10-phenanthroline-5,6-dione

vanillin

Downstream raw materials:

[Cd(4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)-2-methoxyphenol)(naphthalene-1,4-dicarboxylate)]