N,N'-bis(salicylideneamino)ethane-manganese(II)

Base Information

Chemical Name:N,N'-bis(salicylideneamino)ethane-manganese(II)
CAS No.:53177-12-1
Molecular Formula:C₁₆H₁₄MnN₂O₂*Cl
Molecular Weight:356.69
Hs Code.:
Mol file:53177-12-1.mol

Synonyms:Manganese,chloro[[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-,(SP-5-13)-;(Salen)manganese(III) chloride;Chloro(bis(salicylidene)ethylenediamine)manganese;Chloro[N,N'-ethylenebis(salicylideneaminato)]manganese;EUK 8;Manganese(salen)chloride;

Suppliers and Price of N,N'-bis(salicylideneamino)ethane-manganese(II)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
[N,N0-Disalicylidene-1,2-ethanediaminato-(2-)]manganese(III)Chloride
500mg
$ 695.00

Sigma-Aldrich
EUK-8 ≥95% (HPLC)
10mg
$ 106.00

Sigma-Aldrich
EUK-8 ≥95% (HPLC)
50mg
$ 404.00

Crysdot
(Salen)manganese(III)chloride 95%
25g
$ 1350.00

Crysdot
(Salen)manganese(III)chloride 95%
10g
$ 720.00

Crysdot
(Salen)manganese(III)chloride 95%
5g
$ 450.00

Crysdot
(Salen)manganese(III)chloride 95%
1g
$ 150.00

Arctom
(Salen)manganese(III)chloride 98%
1g
$ 216.00

Arctom
(Salen)manganese(III)chloride 98%
250mg
$ 90.00

Arctom
(Salen)manganese(III)chloride 98%
100mg
$ 59.00

Total 14 raw suppliers

Chemical Property of N,N'-bis(salicylideneamino)ethane-manganese(II)

Chemical Property:

Boiling Point:448.8 °C at 760 mmHg
Flash Point:294.1 °C
PSA：70.84000
LogP:0.51620
Storage Temp.:?20°C
Solubility.:H2O: soluble1mg/mL, clear

Purity/Quality:

98%,99%, ^*data from raw suppliers

[N,N0-Disalicylidene-1,2-ethanediaminato-(2-)]manganese(III)Chloride ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Uses [N,N 0-Disalicylidene-1,2-ethanediaminato-(2-)]manganese(III) Chloride is an oxidation catalysts and an enzyme mimetic. It also functions as an intermediate in the synthesis of manganese(III) complexes with fluorinated salen derivatives that exhibits antioxidant properties.

Technology Process of N,N'-bis(salicylideneamino)ethane-manganese(II)

There total 6 articles about N,N'-bis(salicylideneamino)ethane-manganese(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: (N,N'-ethylenebis(salicylideneaminato))Mn_.tplbond.N

: tris(p-bromophenylammoniumyl) hexachloroantimonate

: 125640-71-3,53177-12-1
{Mn(N,N'-ethylenebis(salicylaldiminato))}Cl

: 7727-37-9
nitrogen

Guidance literature:: In fluorobenzene; at 20 ℃; for 3h; Inert atmosphere; Glovebox;
DOI:10.1002/chem.201703153

Reference yield: 73.0%

: manganese(II) chloride tetrahydrate

: 94-93-9
N,N'-ethylenebis(salicylideneimine)

: 125640-71-3,53177-12-1
[N,N'-bis(salicylidene)-1,2-ethanediaminato]Mn(III) chloride

Guidance literature:: In methanol; ethanol; for 2h; Reflux;
DOI:10.1080/15533174.2013.841220

Reference yield:

: 1170-02-1
ethylenediamine-N,N'-bis(2-hydroxyphenylacetic acid)

: 7773-01-5
manganese(ll) chloride

: 53177-12-1
Mn(salen)Cl

Guidance literature:: With tetrabutylammonium hydroxide; In methanol; water; Dissoln. of H4EHPG and (TBA)OH in a mixt. of CH3OH and H2O, addn. of Mn-salt, stirring (3 h, N2), stirring at air for 12 h.; Flash-evapn., recrystn. from DMF.;