4-benzyloxy-7-(tert-butyldimethylsilanyloxy)hept-2-enoic acid methyl ester

Base Information

Chemical Name:4-benzyloxy-7-(tert-butyldimethylsilanyloxy)hept-2-enoic acid methyl ester
CAS No.:1414917-17-1
Molecular Formula:C₂₁H₃₄O₄Si
Molecular Weight:378.584
Hs Code.:

Synonyms:4-benzyloxy-7-(tert-butyldimethylsilanyloxy)hept-2-enoic acid methyl ester

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Chemical Property of 4-benzyloxy-7-(tert-butyldimethylsilanyloxy)hept-2-enoic acid methyl ester

Chemical Property:

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Technology Process of 4-benzyloxy-7-(tert-butyldimethylsilanyloxy)hept-2-enoic acid methyl ester

There total 6 articles about 4-benzyloxy-7-(tert-butyldimethylsilanyloxy)hept-2-enoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 5927-18-4
trimethyl phosphonoacetate

: 1414917-69-3
C₁₈H₃₀O₃Si

: 1414917-17-1
4-benzyloxy-7-(tert-butyldimethylsilanyloxy)hept-2-enoic acid methyl ester

Guidance literature:: With N-ethyl-N,N-diisopropylamine; lithium chloride; In acetonitrile; at 60 ℃; for 1h;
DOI:10.1021/jo302138z

Reference yield:

: 132621-85-3
6-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-1-hexen-3-ol

: 1414917-17-1
4-benzyloxy-7-(tert-butyldimethylsilanyloxy)hept-2-enoic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium hexamethyldisilazane / N,N-dimethyl-formamide / 0.17 h / 0 °C

1.2: 1 h / 0 - 20 °C

2.1: ozone; triphenylphosphine / dichloromethane / 3 h / -78 - 20 °C

3.1: lithium chloride; N-ethyl-N,N-diisopropylamine / acetonitrile / 1 h / 60 °C

With sodium hexamethyldisilazane; ozone; N-ethyl-N,N-diisopropylamine; triphenylphosphine; lithium chloride; In dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo302138z

Reference yield:

: 1414917-16-0
((4-(benzyloxy)hex-5-en-1-yl)oxy)(tert-butyl)dimethylsilane

: 1414917-17-1
4-benzyloxy-7-(tert-butyldimethylsilanyloxy)hept-2-enoic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: ozone; triphenylphosphine / dichloromethane / 3 h / -78 - 20 °C

2: lithium chloride; N-ethyl-N,N-diisopropylamine / acetonitrile / 1 h / 60 °C

With ozone; N-ethyl-N,N-diisopropylamine; triphenylphosphine; lithium chloride; In dichloromethane; acetonitrile;
DOI:10.1021/jo302138z