Acetic acid (4Z,9Z)-(1R,6S,7R,8S)-13-hydroxy-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-trideca-4,9-dienyl ester

Base Information

Chemical Name:Acetic acid (4Z,9Z)-(1R,6S,7R,8S)-13-hydroxy-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-trideca-4,9-dienyl ester
CAS No.:623926-82-9
Molecular Formula:C₄₂H₆₀O₇
Molecular Weight:676.934
Hs Code.:

Acetic acid (4Z,9Z)-(1R,6S,7R,8S)-13-hydroxy-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-trideca-4,9-dienyl ester

Synonyms:Acetic acid (4Z,9Z)-(1R,6S,7R,8S)-13-hydroxy-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-trideca-4,9-dienyl ester

Suppliers and Price of Acetic acid (4Z,9Z)-(1R,6S,7R,8S)-13-hydroxy-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-trideca-4,9-dienyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Acetic acid (4Z,9Z)-(1R,6S,7R,8S)-13-hydroxy-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-trideca-4,9-dienyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Acetic acid (4Z,9Z)-(1R,6S,7R,8S)-13-hydroxy-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-trideca-4,9-dienyl ester

There total 17 articles about Acetic acid (4Z,9Z)-(1R,6S,7R,8S)-13-hydroxy-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-trideca-4,9-dienyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 623926-80-7
Acetic acid (4Z,9Z)-(1R,6S,7R,8S)-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-13-(tetrahydro-pyran-2-yloxy)-trideca-4,9-dienyl ester

: 623926-82-9
Acetic acid (4Z,9Z)-(1R,6S,7R,8S)-13-hydroxy-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-trideca-4,9-dienyl ester

Guidance literature:: With pyridinium p-toluenesulfonate; In ethanol; at 55 ℃;
DOI:10.1016/S0968-0896(03)00186-X

Reference yield:

: 106296-58-6
(2S,3S,4S)-(1-tert-butyldimethylsilanyloxy)-2,4-dimethylhex-5-en-3-ol

: 623926-82-9
Acetic acid (4Z,9Z)-(1R,6S,7R,8S)-13-hydroxy-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-trideca-4,9-dienyl ester

Guidance literature:: Multi-step reaction with 12 steps

1.1: 89 percent / NaH / tetrahydrofuran; dimethylformamide / 48 h / 20 °C

2.1: ozone

2.2: 85 percent / NaBH₄

3.1: 94 percent / I₂; PPh₃; imidazole / diethyl ether; benzene

4.1: 92 percent / benzene / 80 °C

5.1: NaHMDS / tetrahydrofuran

5.2: 61 percent / tetrahydrofuran / -78 - 20 °C

6.1: 89 percent / HF-pyridine; pyridine

7.1: I₂; PPh₃; imidazole

8.1: benzene

9.1: 61 percent / NaHDMS

10.1: 93 percent / TBAF / tetrahydrofuran

11.1: 95 percent / pyridine

12.1: 96 percent / PPTS / ethanol / 55 °C

With pyridine; 1H-imidazole; tetrabutyl ammonium fluoride; iodine; sodium hexamethyldisilazane; pyridinium p-toluenesulfonate; sodium hydride; pyridine hydrogenfluoride; ozone; triphenylphosphine; In tetrahydrofuran; diethyl ether; ethanol; N,N-dimethyl-formamide; benzene; 5.2: Wittig reaction / 9.2: Wittig reaction;
DOI:10.1016/S0968-0896(03)00186-X

Reference yield:

: 184291-95-0
(2S,3S,4S)-1-(tert-butyldimethylsilanyloxy)-3-(4-methoxybenzyloxy)-2,4-dimethyl hex-5-ene

: 623926-82-9
Acetic acid (4Z,9Z)-(1R,6S,7R,8S)-13-hydroxy-7-(4-methoxy-benzyloxy)-1-[(Z)-(1S,2S,3S)-2-(4-methoxy-benzyloxy)-1,3-dimethyl-hepta-4,6-dienyl]-6,8-dimethyl-trideca-4,9-dienyl ester

Guidance literature:: Multi-step reaction with 11 steps

1.1: ozone

1.2: 85 percent / NaBH₄

2.1: 94 percent / I₂; PPh₃; imidazole / diethyl ether; benzene

3.1: 92 percent / benzene / 80 °C

4.1: NaHMDS / tetrahydrofuran

4.2: 61 percent / tetrahydrofuran / -78 - 20 °C

5.1: 89 percent / HF-pyridine; pyridine

6.1: I₂; PPh₃; imidazole

7.1: benzene

8.1: 61 percent / NaHDMS

9.1: 93 percent / TBAF / tetrahydrofuran

10.1: 95 percent / pyridine

11.1: 96 percent / PPTS / ethanol / 55 °C

With pyridine; 1H-imidazole; tetrabutyl ammonium fluoride; iodine; sodium hexamethyldisilazane; pyridinium p-toluenesulfonate; pyridine hydrogenfluoride; ozone; triphenylphosphine; In tetrahydrofuran; diethyl ether; ethanol; benzene; 4.2: Wittig reaction / 8.2: Wittig reaction;
DOI:10.1016/S0968-0896(03)00186-X