(4S)-4-(benzyloxy)hept-6-en-1-ol

Base Information

Chemical Name:(4S)-4-(benzyloxy)hept-6-en-1-ol
CAS No.:1229358-52-4
Molecular Formula:C₁₄H₂₀O₂
Molecular Weight:220.312
Hs Code.:

Synonyms:(4S)-4-(benzyloxy)hept-6-en-1-ol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (4S)-4-(benzyloxy)hept-6-en-1-ol

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Technology Process of (4S)-4-(benzyloxy)hept-6-en-1-ol

There total 7 articles about (4S)-4-(benzyloxy)hept-6-en-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1229358-49-9
(S)-{[4-(benzyloxy)hept-6-en-1-yl]oxy}(tert-butyl)(dimethyl)silane

: 1229358-52-4
(4S)-4-(benzyloxy)hept-6-en-1-ol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 3h; Inert atmosphere;
DOI:10.1002/hlca.201000416

Reference yield:

: 866138-79-6
(2S)-5-{[(tert-butyl)(dimethyl)silyl]oxy}-2-hydroxypentyl 4-methylbenzenesulfonate

: 1229358-52-4
(4S)-4-(benzyloxy)hept-6-en-1-ol

Guidance literature:: Multi-step reaction with 4 steps

1.1: potassium carbonate / methanol / 2 h / Inert atmosphere

2.1: copper(l) iodide / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

3.1: sodium hydride / tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere

3.2: 4 h / 0 - 20 °C / Inert atmosphere

4.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 3 h / 20 °C / Inert atmosphere

With copper(l) iodide; tetrabutyl ammonium fluoride; sodium hydride; potassium carbonate; In tetrahydrofuran; methanol; 2.1: Grignard reaction;
DOI:10.1002/hlca.201000416

Reference yield:

: 127154-84-1
tert-butylpent-4-enyloxydimethylsilane

: 1229358-52-4
(4S)-4-(benzyloxy)hept-6-en-1-ol

Guidance literature:: Multi-step reaction with 6 steps

1.1: AD-mix-α / water; tert-butyl alcohol / 24 h / 0 °C

2.1: di(n-butyl)tin oxide; triethylamine / dichloromethane / 4 h / 20 °C / Inert atmosphere

3.1: potassium carbonate / methanol / 2 h / Inert atmosphere

4.1: copper(l) iodide / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

5.1: sodium hydride / tetrahydrofuran / 0.17 h / 0 °C / Inert atmosphere

5.2: 4 h / 0 - 20 °C / Inert atmosphere

6.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 3 h / 20 °C / Inert atmosphere

With copper(l) iodide; AD-mix-α; tetrabutyl ammonium fluoride; sodium hydride; di(n-butyl)tin oxide; potassium carbonate; triethylamine; In tetrahydrofuran; methanol; dichloromethane; water; tert-butyl alcohol; 4.1: Grignard reaction;
DOI:10.1002/hlca.201000416