methyl (methyl 2,3,4-tri-O-methyl-α-L-idopyranosyluronate)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-C-(sodium sulfonatomethyl)-α-D-glucopyranoside

Base Information

Chemical Name:methyl (methyl 2,3,4-tri-O-methyl-α-L-idopyranosyluronate)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-C-(sodium sulfonatomethyl)-α-D-glucopyranoside
CAS No.:1333164-18-3
Molecular Formula:C₃₂H₄₃O₁₄S*Na
Molecular Weight:706.741
Hs Code.:

Synonyms:methyl (methyl 2,3,4-tri-O-methyl-α-L-idopyranosyluronate)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-C-(sodium sulfonatomethyl)-α-D-glucopyranoside

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Chemical Property of methyl (methyl 2,3,4-tri-O-methyl-α-L-idopyranosyluronate)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-C-(sodium sulfonatomethyl)-α-D-glucopyranoside

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Technology Process of methyl (methyl 2,3,4-tri-O-methyl-α-L-idopyranosyluronate)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-C-(sodium sulfonatomethyl)-α-D-glucopyranoside

There total 5 articles about methyl (methyl 2,3,4-tri-O-methyl-α-L-idopyranosyluronate)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-C-(sodium sulfonatomethyl)-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1161723-66-5
C₃₁H₄₂O₁₄S

: 74-88-4
methyl iodide

: 1333164-19-4
methyl (methyl 4-deoxy-2,3-di-O-methyl-α-L-threo-hex-4-enopyranosyluronate)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-C-(sodium sulfonatomethyl)-α-D-glucopyranoside

: 1333164-18-3
methyl (methyl 2,3,4-tri-O-methyl-α-L-idopyranosyluronate)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-C-(sodium sulfonatomethyl)-α-D-glucopyranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 2h;
DOI:10.1016/j.carres.2011.06.021

Reference yield:

: 1161723-65-4
C₃₃H₄₆O₁₄S

: 1333164-18-3
methyl (methyl 2,3,4-tri-O-methyl-α-L-idopyranosyluronate)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-C-(sodium sulfonatomethyl)-α-D-glucopyranoside

Guidance literature:: With sodium iodide; In acetone; at 20 ℃; for 2h;
DOI:10.1016/j.carres.2011.06.021

Reference yield:

: C₁₄H₂₀O₁₀

: 1333164-19-4
methyl (methyl 4-deoxy-2,3-di-O-methyl-α-L-threo-hex-4-enopyranosyluronate)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-C-(sodium sulfonatomethyl)-α-D-glucopyranoside

: 1333164-18-3
methyl (methyl 2,3,4-tri-O-methyl-α-L-idopyranosyluronate)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-C-(sodium sulfonatomethyl)-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: benzylamine / tetrahydrofuran / 4 h

2.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 0.5 h / 0 °C

3.1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 0.25 h / -20 - 0 °C / Molecular sieve

3.2: 2 h / 20 °C

4.1: sodium hydride / N,N-dimethyl-formamide / 2 h / 0 - 20 °C

With trimethylsilyl trifluoromethanesulfonate; sodium hydride; 1,8-diazabicyclo[5.4.0]undec-7-ene; benzylamine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.carres.2011.06.021