1-methyl-1-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>cyclohex-2-en-4-one

Base Information

Chemical Name:1-methyl-1-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>cyclohex-2-en-4-one
CAS No.:122444-66-0
Molecular Formula:C₁₄H₂₀O₅S
Molecular Weight:300.376
Hs Code.:

Synonyms:1-methyl-1-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>cyclohex-2-en-4-one

Suppliers and Price of 1-methyl-1-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>cyclohex-2-en-4-one

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-methyl-1-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>cyclohex-2-en-4-one

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Technology Process of 1-methyl-1-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>cyclohex-2-en-4-one

There total 1 articles about 1-methyl-1-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>cyclohex-2-en-4-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 15.0%

: 122444-67-1
C₁₄H₂₀O₅S

: 122444-66-0
1-methyl-1-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>cyclohex-2-en-4-one

Guidance literature:: With copper dichloride; In ethanol; for 6h; Ambient temperature;
DOI:10.1021/jo00280a039

Reference yield: 87.0%

: 75-16-1
methylmagnesium bromide

: 122444-66-0
1-methyl-1-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>cyclohex-2-en-4-one

: 122444-68-2
1,4-dimethyl-4-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>-2-cyclohexen-1-ol

Guidance literature:: In tetrahydrofuran; diethyl ether; at -78 ℃; for 4h;
DOI:10.1021/jo00280a039

Reference yield:

: 122444-66-0
1-methyl-1-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>cyclohex-2-en-4-one

: 122444-69-3
3,6-dimethyl-6-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>-2-cyclohexen-1-one

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / tetrahydrofuran; diethyl ether / 4 h / -78 °C

2: 87 percent / pyridinium chlorochromate / CH₂Cl₂ / 3 h / Ambient temperature

With pyridinium chlorochromate; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/jo00280a039