4-(trifluoromethyl)phenylbromonium bis[(trifluoromethyl)sulfonyl]methylide

Base Information

• Chemical Name: 4-(trifluoromethyl)phenylbromonium bis[(trifluoromethyl)sulfonyl]methylide
• CAS No.: 905453-88-5
• Molecular Formula: C₁₀H₄BrF₉O₄S₂
• Molecular Weight: 503.161
• Mol file: 905453-88-5.mol

Synonyms:4-(trifluoromethyl)phenylbromonium bis[(trifluoromethyl)sulfonyl]methylide

Chemical Property of 4-(trifluoromethyl)phenylbromonium bis[(trifluoromethyl)sulfonyl]methylide

Chemical Property:

Purity/Quality:

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Technology Process of 4-(trifluoromethyl)phenylbromonium bis[(trifluoromethyl)sulfonyl]methylide

There total 1 articles about 4-(trifluoromethyl)phenylbromonium bis[(trifluoromethyl)sulfonyl]methylide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

bis(trifluoromethanesulfonyl)methane (428-76-2) + difluoro[4-(trifluoromethyl)phenyl]-λ3-bromane (206753-28-8) → 4-(trifluoromethyl)phenylbromonium bis[(trifluoromethyl)sulfonyl]methylide (905453-88-5)

Guidance literature:

In acetonitrile; at 0 ℃; for 3h;

DOI:10.1021/ja063492+

Reference yield: 100.0%

4-(trifluoromethyl)phenylbromonium bis[(trifluoromethyl)sulfonyl]methylide (905453-88-5) + 4-tolyl iodide (624-31-7) → p-methylphenyliodonium bis(trifluoromethylsulfonyl)methylide (1010117-79-9)

Guidance literature:

dirhodium tetraacetate; at 40 ℃; for 0.0833333h;

DOI:10.1021/ja074624h

Reference yield: 100.0%

4-(trifluoromethyl)phenylbromonium bis[(trifluoromethyl)sulfonyl]methylide (905453-88-5) + N-Benzylpiperidine (2905-56-8) → N-benzylpiperidinium bis[(trifluoromethyl)sulfonyl]methanide

Guidance literature:

In dichloromethane;

DOI:10.1021/ja063492+

upstream raw materials:

bis(trifluoromethanesulfonyl)methane

difluoro[4-(trifluoromethyl)phenyl]-λ³-bromane

Downstream raw materials:

p-chlorophenylbromonium bis(trifluoromethylsulfonyl)methylide

phenylbromonium bis(trifluoromethylsulfonyl)methylide

p-methoxyphenylbromonium bis(trifluoromethylsulfonyl)methylide

phenyliodonium bis(trifluoromethylsulfonyl)methylide