C₆₅H₁₁₁ClO₁₃Si₂

Base Information

Chemical Name:C₆₅H₁₁₁ClO₁₃Si₂
CAS No.:1293966-55-8
Molecular Formula:C₆₅H₁₁₁ClO₁₃Si₂
Molecular Weight:1192.21
Hs Code.:

C<sub>65</sub>H<sub>111</sub>ClO<sub>13</sub>Si<sub>2</sub>

Synonyms:C₆₅H₁₁₁ClO₁₃Si₂

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Chemical Property of C₆₅H₁₁₁ClO₁₃Si₂

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Technology Process of C₆₅H₁₁₁ClO₁₃Si₂

There total 47 articles about C₆₅H₁₁₁ClO₁₃Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 1293966-80-9
C₅₉H₉₇ClO₁₃Si

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1293966-55-8
C₆₅H₁₁₁ClO₁₃Si₂

Guidance literature:: With 1H-imidazole; dmap; In dichloromethane; at 40 ℃; for 15h; Inert atmosphere;
DOI:10.1021/ol2007296

Reference yield:

: 1293966-33-2
C₁₉H₂₄O₅S

: 1293966-55-8
C₆₅H₁₁₁ClO₁₃Si₂

Guidance literature:: Multi-step reaction with 10 steps

1.1: samarium diiodide / tetrahydrofuran; methanol / 0.5 h / -10 °C / Inert atmosphere

2.1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere

3.1: potassium carbonate / tetrahydrofuran; methanol / 0.5 h / 0 °C / Inert atmosphere

4.1: 1H-imidazole; dmap / dichloromethane / 12 h / 20 °C / Inert atmosphere

5.1: pyridine / acetonitrile / 0.5 h / 0 °C / Inert atmosphere

6.1: water; potassium acetate / acetonitrile / 12 h / 0 °C / Inert atmosphere

7.1: tert.-butyl lithium / diethyl ether; pentane / 0.5 h / -78 °C / Inert atmosphere

7.2: 2 h / -78 °C / Inert atmosphere

8.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

9.1: dmap; camphor-10-sulfonic acid; dicyclohexyl-carbodiimide / dichloromethane / 15 h / 30 °C

10.1: 1H-imidazole; dmap / dichloromethane / 15 h / 40 °C / Inert atmosphere

With pyridine; 1H-imidazole; dmap; samarium diiodide; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; water; tert.-butyl lithium; potassium acetate; potassium carbonate; dicyclohexyl-carbodiimide; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; acetonitrile; pentane; 2.1: Mitsunobu reaction / 5.1: Pummerer rearrangement;
DOI:10.1021/ol2007296

Reference yield:

: 1293966-31-0
(4S,5S)-2,2-dimethyl-4-((S)-oxiran-2-yl)-5-vinyl-1,3-dioxolane

: 1293966-55-8
C₆₅H₁₁₁ClO₁₃Si₂

Guidance literature:: Multi-step reaction with 13 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -20 °C / Inert atmosphere

1.2: 1 h / -20 °C / Inert atmosphere

2.1: ethylmagnesium bromide; lithium chloride / tetrahydrofuran; diethyl ether / 24 h / 20 °C / Inert atmosphere

3.1: water; calcium carbonate; methyl iodide / acetonitrile / 15 h / 40 °C / Inert atmosphere

4.1: samarium diiodide / tetrahydrofuran; methanol / 0.5 h / -10 °C / Inert atmosphere

5.1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere

6.1: potassium carbonate / tetrahydrofuran; methanol / 0.5 h / 0 °C / Inert atmosphere

7.1: 1H-imidazole; dmap / dichloromethane / 12 h / 20 °C / Inert atmosphere

8.1: pyridine / acetonitrile / 0.5 h / 0 °C / Inert atmosphere

9.1: water; potassium acetate / acetonitrile / 12 h / 0 °C / Inert atmosphere

10.1: tert.-butyl lithium / diethyl ether; pentane / 0.5 h / -78 °C / Inert atmosphere

10.2: 2 h / -78 °C / Inert atmosphere

11.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

12.1: dmap; camphor-10-sulfonic acid; dicyclohexyl-carbodiimide / dichloromethane / 15 h / 30 °C

13.1: 1H-imidazole; dmap / dichloromethane / 15 h / 40 °C / Inert atmosphere

With pyridine; 1H-imidazole; dmap; n-butyllithium; samarium diiodide; camphor-10-sulfonic acid; ethylmagnesium bromide; tetrabutyl ammonium fluoride; water; tert.-butyl lithium; potassium acetate; potassium carbonate; dicyclohexyl-carbodiimide; triphenylphosphine; calcium carbonate; lithium chloride; diethylazodicarboxylate; methyl iodide; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; acetonitrile; pentane; 5.1: Mitsunobu reaction / 8.1: Pummerer rearrangement;
DOI:10.1021/ol2007296